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溶胶凝胶旋涂方法制备Dy~(3+)掺杂的LaVO_4薄膜(英文)
引用本文:吴丹丹,马永青,张贤,钱仕兵,董玉琴,郑赣鸿.溶胶凝胶旋涂方法制备Dy~(3+)掺杂的LaVO_4薄膜(英文)[J].安徽大学学报(自然科学版),2012,36(3):47-53.
作者姓名:吴丹丹  马永青  张贤  钱仕兵  董玉琴  郑赣鸿
作者单位:安徽大学物理与材料科学学院,安徽合肥,230039
基金项目:安徽省教育厅自然科学基金重点资助项目,安徽省信息材料与器件重点实验室开放基金资助项目,安徽大学“211工程”基金重点资助项目,安徽大学青年教师基金资助项目
摘    要:通过向溶胶前躯体溶液中加入与金属阳离子不同比例的柠檬酸,用溶胶凝胶旋涂方法制备透明并且致密的Dy3+掺杂的LaVO4薄膜.当柠檬酸与金属阳离子的比例为2∶1时,制成的薄膜对可见和红外光的透过率达到90%左右,以波长为310 nm的光激发薄膜时可以得到对应于4F9/2-6H15/2和4F9/2-6H13/2跃迁的波长为484 nm(蓝光)和576 nm(黄光)的发射波,讨论Dy3+掺杂的LaVO4薄膜在染料敏化太阳能电池里的潜在应用.

关 键 词:LaVO  Dy+  发光薄膜  旋涂方法  光致发光

Dy3+ doped LaVO4 films fabricated by a sol-gel spin-coating method
WU Dan-dan , MA Yong-qing , ZHANG Xian , QIAN Shi-bing , DONG Yu-qin , ZHENG Gan-hong.Dy3+ doped LaVO4 films fabricated by a sol-gel spin-coating method[J].Journal of Anhui University(Natural Sciences),2012,36(3):47-53.
Authors:WU Dan-dan  MA Yong-qing  ZHANG Xian  QIAN Shi-bing  DONG Yu-qin  ZHENG Gan-hong
Institution:(School of Physics and Materials Science,Anhui University,Hefei 230039,China)
Abstract:Transparent and compact LaVO4:Dy3+ thin films were prepared by a spin-coating method with different ratios of citric acid to metal ions in the precursor solution.The transmittance of LaVO4:Dy3+ thin films reached around 90% in the visible and infrared region with the optimum ratio 2∶1 of citric acid to metal cation.The LaVO4:Dy3+ films were excited by the 310 nm ultraviolet light and emitted the characteristic emissions of Dy3+ peaking at 484 nm(blue) and 576 nm(yellow) due to the transitions of 4F9/2-6H15/2 and 4F9/2-6H13/2,respectively.The potential application of LaVO4:Dy3+ film in the dye-sensitized solar cell(DSSC) was also discussed.
Keywords:LaVO4:Dy3+  luminescent film  spin-coating  photoluminescence
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