| 30%TBP-煤油体系中锆的红外光谱特性 |
| |
| 引用本文： | 俞誉福,周亚康,秦启宗. 30%TBP-煤油体系中锆的红外光谱特性[J]. 复旦学报(自然科学版), 1988, 0(1) |
| |
| 作者姓名： | 俞誉福 周亚康 秦启宗 |
| |
| 作者单位： | 复旦大学原子核科学系，复旦大学原子核科学系，复旦大学原子核科学系 一九八五届本科毕业生 |
| |
| 摘 要： | 本文报道了2000cm~(-1)至250cm~(-1)范围内,30%TBP-煤油、30%TBP-煤油-HNO_3、30%TBP-煤油-Zr(NO_3)_4、Zr(NO_3)_4(DBP)_2以及有机锆络合物沉淀的红外光谱,并且对其中主要吸收带成分作了解释,考察了放置时间对30%TBP-煤油-Zr(NO_3)_4红外光谱的影响,在陈化的有机相中未发现有新的红外官能团。研究结果表明,从陈化有机相中析出的含锆沉淀物,其红外光谱特性与人工制备的Zr(NO_3)_4(DBP)_2的性质非常相似。
|
| 关 键 词： | 锆 红外光谱 TBP 煤油。 |
INFRARED STUDY OF ZIRCONIUM NITRATE IN 30% TBP-KEROSENE SOLUTION |
| |
| Yu Yufu,Zhou Yakang,Qin Qizong,. INFRARED STUDY OF ZIRCONIUM NITRATE IN 30% TBP-KEROSENE SOLUTION[J]. Journal of Fudan University(Natural Science), 1988, 0(1) |
| |
| Authors: | Yu Yufu Zhou Yakang Qin Qizong |
| |
| Affiliation: | Department of Nuclear Science |
| |
| Abstract: | The Fourier transform infrared spectra of the systems of 30% TBP-kerosene,30% TBP-kerosene-HNO_3, 30% TBP-kerosene_Zr(NO_3)_4, Zr(NO_3)_4 (DBP)_2 andorganic zirconium complex in the region of 2000 cm~(-1) to 250 cm~(-1) are presented alongwith the assignment of the main components of the spectra to the functional groups. The effect of aging on the infrared spectra of 30% TBP-kerosene-Zr(NO_3)_4 hasbeen examined. During three months of aging no new absorption bands developed inthe zirconium-TBP-kerosene solution. Zirconium precipitated from aged organicsolution exhibited an infrared spectrum almost identical with the spectrum of zirconiumnitrate dibutyl phosphate complex. |
| |
| Keywords: | TBP kerosene zirconium infrared spectrum. |
| 本文献已被 CNKI 等数据库收录！ |
|
