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简法高立体选择性合成d-异蒲勒醇
引用本文:张殊佳,刘群,杨智蕴,胡玉兰,刘萍.简法高立体选择性合成d-异蒲勒醇[J].东北师大学报(自然科学版),1994(1).
作者姓名:张殊佳  刘群  杨智蕴  胡玉兰  刘萍
作者单位:东北师范大学化学系
摘    要:以溴化锌为催化剂,1-香茅醛经环合得到了d-异蒲勒醇,所用催化剂系填充在柱子里,且可重复使用,该反应的产率高于75%,产物的旋光纯度可达95%。

关 键 词:d-异蒲勒醇  催化剂填充柱  高旋光纯度

A Simple Method for the Highly stereoselective preparation of d-Isopulegol
ZhangShujia, Liu Qun,Yang Zhiyun,Hu Yulan,Liu Ping.A Simple Method for the Highly stereoselective preparation of d-Isopulegol[J].Journal of Northeast Normal University (Natural Science Edition),1994(1).
Authors:ZhangShujia  Liu Qun  Yang Zhiyun  Hu Yulan  Liu Ping
Abstract:d-Isopulegol was prepared via cyclization of l-citronellal catalyzed by zinc bromide. The catalyst was packed in a column and can be used repeatedly. The yield was higher than 75% and the optical purity reached to more than95%.
Keywords:d-Isopulegol  column packed with catalyst  high optical purity
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