| 键联双噁唑类化合物质谱的研究 |
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| 引用本文： | 张文勤,游德华,朱禾蕙,张西慧. 键联双噁唑类化合物质谱的研究[J]. 天津大学学报(自然科学与工程技术版), 1996, 0(6) |
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| 作者姓名： | 张文勤 游德华 朱禾蕙 张西慧 |
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| 基金项目： | 天津大学优秀人才启动基金 |
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| 摘 要： | 测试了２９种键联双唑类化合物的质谱，利用亚稳离子技术研究了其质谱裂分过程．结果表明，上述化合物大多裂分过程都是先从唑环开始的．唑环邻位有甲基时，甲基易参与重排，并且发现该类化合物易形成双电荷分子离子，共轭体系越大，双电荷分子离子峰的强度越高．
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| 关 键 词： | 键联双噁唑，质谱，裂分机理，双电荷分子离子 |
STUDY ON THE MASS SPECTRA OF BOND-LINKED BISOXAZOLES |
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| Zhang Wenqin, You Dehua, Zhu Hehui, Zhang Xihui. STUDY ON THE MASS SPECTRA OF BOND-LINKED BISOXAZOLES[J]. Journal of Tianjin University(Science and Technology), 1996, 0(6) |
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| Authors: | Zhang Wenqin You Dehua Zhu Hehui Zhang Xihui |
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| Affiliation: | Dept.of Chemistry |
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| Abstract: | The mass spectra of twenty-nine bond-linked bisoxazoles were measured. The fragmentation pathways were studied by the metastable ion technique. The results show that most of the fragmentation reactions begin at oxazole rings and the methyl group will take part in the fragmentation rearrangement when it is in the o-position of the oxazole ring. We also found that double-charge molecular ions form easily among these compounds. The larger the conjugationsystem is, the higher the double-charge molecular ion peak is. |
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| Keywords: | bond-linked bisoxazole mass spectrum fragmentation mechanism double-charge molecular ion |
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