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低价钛试剂引起的酮与腈的还原偶联反应
引用本文:周龙虎,史达清. 低价钛试剂引起的酮与腈的还原偶联反应[J]. 徐州师范大学学报(自然科学版), 1995, 0(1)
作者姓名:周龙虎  史达清
摘    要:在低价钛(TiCl4-Zn)试剂作用下,腈与二芳酮发生分子间交叉还原偶联反应生成酮,而腈与1,3-二酮反应生成取代吡咯。

关 键 词:低价钛,腈,芳酮,吡咯衍生物,交叉还原偶联

Reductive Coupling Reaction of Aromatic Ketones with Nitriles Induced by Low-valent Titanium
Zhou Longhu,Shi Daqing. Reductive Coupling Reaction of Aromatic Ketones with Nitriles Induced by Low-valent Titanium[J]. Journal of Xuzhou Normal University(Natural Science Edition), 1995, 0(1)
Authors:Zhou Longhu  Shi Daqing
Affiliation:Zhou Longhu;Shi Daqing
Abstract:The intermolecular reductive cross-coupling of diaromatic ketones with nitriles induced by low-valent titanium reagent(TiCl4-Zn) affords ketones. However, in the presence of low-valent titanium, nitriles and 1,3-diketone can be coupled to substituted pyrroles.
Keywords:Low-valent titanium   nitrile   aromatic ketone   substituted pyrrole   reductive crosscoupling
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