| 低价钛试剂引起的酮与腈的还原偶联反应 |
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| 引用本文： | 周龙虎,史达清.低价钛试剂引起的酮与腈的还原偶联反应[J].徐州师范大学学报(自然科学版),1995(1). |
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| 作者姓名： | 周龙虎 史达清 |
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| 摘 要： | 在低价钛（ＴｉＣｌ４－Ｚｎ）试剂作用下，腈与二芳酮发生分子间交叉还原偶联反应生成酮，而腈与１，３－二酮反应生成取代吡咯。
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| 关 键 词： | 低价钛，腈，芳酮，吡咯衍生物，交叉还原偶联 |
Reductive Coupling Reaction of Aromatic Ketones with Nitriles Induced by Low-valent Titanium |
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| Zhou Longhu,Shi Daqing.Reductive Coupling Reaction of Aromatic Ketones with Nitriles Induced by Low-valent Titanium[J].Journal of Xuzhou Normal University(Natural Science Edition),1995(1). |
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| Authors: | Zhou Longhu Shi Daqing |
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| Institution: | Zhou Longhu;Shi Daqing |
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| Abstract: | The intermolecular reductive cross-coupling of diaromatic ketones with nitriles induced by low-valent titanium reagent(TiCl4-Zn) affords ketones. However, in the presence of low-valent titanium, nitriles and 1,3-diketone can be coupled to substituted pyrroles. |
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| Keywords: | Low-valent titanium nitrile aromatic ketone substituted pyrrole reductive crosscoupling |
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