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TPU/POE共混体系相分离过程的ATR-FTIR研究
引用本文:李冲,魏永春,罗伟昂,张逢君,刘洪博,廖正福,陈旭东.TPU/POE共混体系相分离过程的ATR-FTIR研究[J].华南师范大学学报(自然科学版),2011,0(2):70-0.
作者姓名:李冲  魏永春  罗伟昂  张逢君  刘洪博  廖正福  陈旭东
作者单位:1.1.北京理工大学珠海学院
摘    要:探讨了一种新的共混体系热塑性聚氨酯(TPU)/聚乙烯-辛烯共聚物(POE)共混体系,在相分离过程中衰减全反射傅里叶变换红外光谱(ATR-FTIR),结果发现:对于不相容TPU/POE体系,随着热老化时间的增加,ATR-FT-IR特征峰面积也逐渐增加(温度较低除外),温度较高时则先增加后降低;而PU/POE/POE-g-...

关 键 词:TPU/POE共混物  衰减全反射傅里叶变换红外光谱  相分离  热老化
收稿时间:2010-09-08

STUDIES ON TPU/POE'S PHASE SEPARATION BY ATR-FTIR
LI Chong,WEI Yongchun,LUO Weiang,ZHANG Fengjui,LIU Hongbo,LIAO Zhengfu,CHEN Xudong.STUDIES ON TPU/POE'S PHASE SEPARATION BY ATR-FTIR[J].Journal of South China Normal University(Natural Science Edition),2011,0(2):70-0.
Authors:LI Chong  WEI Yongchun  LUO Weiang  ZHANG Fengjui  LIU Hongbo  LIAO Zhengfu  CHEN Xudong
Abstract:The process of phase separation for a new thermoplastic polyurethane/poly (ethylene-octene) (TPU/POE) blending system was studied by Fourier Transform Attenuated Total Reflection Infrared Spectroscopy (ATR-FTIR). The results show that, for the incompatible TPU/POE system, the area of characteristic peak on ATR-FTIR increased with the increase of thermal aging time (except at quite low temperatures), while it increased first and then decreased at higher temperatures. For a PU/POE/POE-g-MA system, the area decreased due to the addition of compatibilizers.
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