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稀土—罗丹明配合物的合成和性质的研究
引用本文:李林书 杨燕生. 稀土—罗丹明配合物的合成和性质的研究[J]. 中山大学学报(自然科学版), 1991, 30(2): 12-18
作者姓名:李林书 杨燕生
作者单位:河北师范学院化学系,河北师范学院化学系,中山大学化学系,中山大学化学系
摘    要:本文报道12种稀土(Y、La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Yb)—罗丹明B的固体配合物制备,通过元素分析、溶解度及摩尔电导测定、差热热重分析、X-射线衍射、红外、紫外、可见、荧光光谱以及~1HNMR谱等对它们的配位作用和性质进行了研究。

关 键 词:稀土硝酸盐  罗丹明B  稀土配合物

Study on the Synthesis and Properties of Coordination Compounds for Rare Earths with Rhodamine B
Li Linshu,Wang Ruifen,Yang Yansheng,Li Yuangying. Study on the Synthesis and Properties of Coordination Compounds for Rare Earths with Rhodamine B[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 1991, 30(2): 12-18
Authors:Li Linshu  Wang Ruifen  Yang Yansheng  Li Yuangying
Affiliation:Li Linshu;Wang Ruifen;Yang Yansheng;Li Yuangying Department of Chemistry
Abstract:Twelve solid coordination compounds of RE(Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Er,Yb)with Rhodamine B were prepared.Their compositions wereconfirmed by elemental analysis,molar conductance,and thermal analysis.Coordination between the ligand and the RE ion was proved by X-ray powderdiffraction and UV spectra.The coordinated function groups of the ligand wereexamined by IR and ~1H NMR spectra.
Keywords:rare earth nitrates  Rhodamine B  rare earth coordination compounds
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