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水热法KTP晶体生长及形貌特征
引用本文:邱志惠,霍汉德,阮青锋,覃西杰,卢福华,张良钜,周卫宁,雷威,张昌龙.水热法KTP晶体生长及形貌特征[J].广西师范大学学报(自然科学版),2006,24(2):52-55.
作者姓名:邱志惠  霍汉德  阮青锋  覃西杰  卢福华  张良钜  周卫宁  雷威  张昌龙
作者单位:广西师范大学,化学化工学院,广西,桂林,541004;桂林地质矿产研究院,广西,桂林,541004;桂林工学院,资源与环境工程系,广西,桂林,541004
基金项目:国家自然科学基金 , 广西青年科学基金 , 广西科技能力建设基金 , 广西自然科学基金
摘    要:晶体宏观形态和表面微形貌特征是晶体生长机制的具体反映,通过对晶体形貌特征的研究,探寻晶体生长的规律,为进一步改善晶体的质量打下基础。通过对水热法KTP晶体(磷酸钛氧钾,KT iOPO4,KTP)宏观形态和表面微形貌的研究,首次发现了KTP晶体中高指数晶面和{100}单形晶面上的螺旋生长纹,探讨发现高指数晶面和{100}单形晶面上螺旋纹的形成原因主要是溶液的过饱和度偏低以及籽晶的悬挂方式,为生长高质量的KTP晶体,提出了增大原材料溶解区与晶体生长区的温度差、改变籽晶的切向和悬挂方向等建议。

关 键 词:磷酸钛氧钾  KTP晶体  水热法  晶体形貌
文章编号:1001-6600(2006)02-0052-04
收稿时间:2005-11-19
修稿时间:2005年11月19

Growth and Morphology of Hydrothermal KTP Crystal
QIU Zhi-hui,HUO Han-de,RUAN Qing-feng,QIN Xi-jie,LU Fu-hua,ZHANG Liang-ju,ZHOU Wei-ning,LEI Wei,ZHANG Chang-long.Growth and Morphology of Hydrothermal KTP Crystal[J].Journal of Guangxi Normal University(Natural Science Edition),2006,24(2):52-55.
Authors:QIU Zhi-hui  HUO Han-de  RUAN Qing-feng  QIN Xi-jie  LU Fu-hua  ZHANG Liang-ju  ZHOU Wei-ning  LEI Wei  ZHANG Chang-long
Institution:1. College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin 541004,China ; 2. Guilin Research Institute of Geology for Mineral Resources ,Guilin 541004 ,China;3. Department of Resources and Environmental Engineering,Guilin Institute of Technology,Guilin 541004,China
Abstract:The characteristics of crystal's macroscopic and micro morphology are mirrors of the mechanism of crystal growth.The study of macroscopic and micro morphology of the crystal is not only an aid to find the truth of the crystal growth,but also some help to improve the quality of the grown crystals.Some unusual crystal faces with large indices and the spiral growth striations on {100} in hydrothermal grown KTP crystal were reported and the causes were discussed,such as,lower concentration of supersaturated solution and the directions of seed crystal.Some suggestions on improving the technics of the crystal growth of KTP were given.
Keywords:potassium titanium phosphate  KTP crystal  hydrothermal  crystal morphology
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