| 甲氧基乙醇红外多光子解离机理的研究 |
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| 引用本文： | 郭用猷,顾月姝,董金华,侯正林,印永嘉.甲氧基乙醇红外多光子解离机理的研究[J].山东大学学报(理学版),1991(4). |
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| 作者姓名： | 郭用猷 顾月姝 董金华 侯正林 印永嘉 |
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| 作者单位： | 山东大学化学系，山东大学化学系，山东大学化学系，山东大学化学系，山东大学化学系 |
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| 摘 要： | 用TEA CO_2激光器研究了甲氧基乙醇(CH_3OCH_2CH_2OH)的红外多光子解离机理.探讨了解离机理与分子的电荷分布和断裂键的势能曲线之间的关系.测得了解离率与激光能流的关系,得到解离阈值约为0.9J/cm~2.
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| 关 键 词： | 红外多光子解离 甲氧基乙醇 解离机理 |
THE DISSOCIATION MECHANISM STUDY OF METHYL CELLOSOLVE BY INFRARED MULTIPHOTON ABSORPTION |
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| Guo Yongyou,Gu Yuezhu,Dong Jinhua,Hou Zhenglin and Yin Yongjia.THE DISSOCIATION MECHANISM STUDY OF METHYL CELLOSOLVE BY INFRARED MULTIPHOTON ABSORPTION[J].Journal of Shandong University,1991(4). |
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| Authors: | Guo Yongyou Gu Yuezhu Dong Jinhua Hou Zhenglin and Yin Yongjia |
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| Abstract: | The infrared multiphoton dissociation mechanism of methyl cellosolve (CH_3OCH_2CH_2OH) has been studied by using a TEA CO_2 laser. We have also explored the dependence of dissociation mechanism on charge distribution and potential energy curve of broken bond. The dissociation degree as a function of energy density has been determined. The threshold energy is 0.9J/cm~2. |
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| Keywords: | infrared multiphoton dissociation methyl cellosolve dissociation degree |
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