| 基于Ni@Pt燃料电池型甲醛电化学传感器的研究 |
| |
| 引用本文： | 陈子豪,廖志远,吴雨驰,孙良良,许沧粟,张嘉俊,刘忠贵,熊海龙. 基于Ni@Pt燃料电池型甲醛电化学传感器的研究[J]. 上海理工大学学报, 2024, 45(1): 26-33 |
| |
| 作者姓名： | 陈子豪 廖志远 吴雨驰 孙良良 许沧粟 张嘉俊 刘忠贵 熊海龙 |
| |
| 作者单位： | 景德镇陶瓷大学 材料科学与工程学院, 江西 景德镇 333000;景德镇陶瓷大学 材料科学与工程学院, 江西 景德镇 333000;浙江大学 清洁能源利用国家重点实验室 能源工程学院, 浙江 杭州 310027 |
| |
| 基金项目： | 江西省厅级项目（20192 bbel50020 bbhl80014 20192)；景德镇市科技局资助项目（20182Gyed011-15）；大学生创新性承担项目（202010408003202104801 X 3；S202010408002X；S202210408052X) |
| |
| 摘 要： | 通过热裂解和氢还原制备了Ni纳米颗粒，并在酸性溶液中通过液相置换合成了核壳 Ni@Pt-800。采用喷涂法将催化剂作为阴极涂层附着在质子交换膜上，阳极涂层为商业Pt/C。采用透射电子显微镜、X射线光电子能谱仪、X射线衍射仪对催化剂结构进行表征。结果表明，Ni@Pt-800对甲醛的响应分别是Ni@Pt和其他干扰气体的4.95倍和25倍。在0～135×10?6范围内，甲醛的氧化峰电流与浓度有着良好的线性关系，其线性回归方程为：△i=0.00103×10?6－0.006 61，相关系数为0.98。
|
| 关 键 词： | 甲醛 质子交换膜 电化学传感器 |
| 收稿时间： | 2023-11-17 |
Study on Ni@Pt-based fuel cell-type electrochemical sensor for formaldehyde |
| |
| CHEN Zihao,LIAO Zhiyuan,WU Yuchi,SUN Liangliang,XU Cangsu,ZHANG Jiajun,LIU Zhonggui,XIONG Hailong. Study on Ni@Pt-based fuel cell-type electrochemical sensor for formaldehyde[J]. Journal of University of Shanghai For Science and Technology, 2024, 45(1): 26-33 |
| |
| Authors: | CHEN Zihao LIAO Zhiyuan WU Yuchi SUN Liangliang XU Cangsu ZHANG Jiajun LIU Zhonggui XIONG Hailong |
| |
| Affiliation: | School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333000, China;School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen 333000, China;College of Energy Engineering, State key laboratory of Clean Energy Utilization Zhejiang University, Hangzhou 310027, China |
| |
| Abstract: | Ni nanoparticles were prepared by thermal cracking and hydrogen reduction, and coreshell Ni@Pt-800 was synthesized by liquid-phase substitution in acidic solution. The catalysts were attached as cathodic coatings onto a proton exchange membrane using the spray method, and the anodic coatings were commercial Pt/C. The catalysts were characterized by transmission electron microscope, X-ray photoelectron spectrometer, and X-ray diffractometer. The results suggest that the response of Ni@Pt-800 to formaldehyde is 4.95 times of Ni@Pt and 25 times of the other interfering gases. In the range of 0-135×10?6, there is a good linear relationship between the oxidation peak current and concentration of formaldehyde, and the linear regression equation is: △i=0.00103×10?6－0.006 61, with a correlation coefficient of 0.98. |
| |
| Keywords: | formaldehyde proton exchange membranes electrochemical sensor |
|
| 点击此处可从《上海理工大学学报》浏览原始摘要信息 |
|
点击此处可从《上海理工大学学报》下载免费的PDF全文 |
|
