| 配合平衡离子分布的尝试迭代法求解 |
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| 引用本文： | 王清成,何文猛,尹光福. 配合平衡离子分布的尝试迭代法求解[J]. 四川大学学报(自然科学版), 2000, 34(6): 906-910 |
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| 作者姓名： | 王清成 何文猛 尹光福 |
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| 作者单位： | 1. 西南工学院材料科学与工程系，绵阳 621002
2. 四川大学无机材料系，成都 610065 |
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| 摘 要： | 用经典迭代法求解配位体不过量的配合平衡系统的离子分布十分困难，而用作者提出的尝试迭代法却能顺利求解，尝试迭代法的作法是：从千千万万组离子浓度的取值中，用尝试法筛选出若干组满足尝试公式的离子浓度，再用失代法确认出其中正确的那一组。
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| 关 键 词： | 尝试迭代法 配合平衡 离子分布 配位体不过量 求解 离子浓度 配位效应 |
| 文章编号： | 0490-6756(2000)06-0906-05 |
EVALUATION ON IONIC DISTRIBUTION FOR THE COMPICATED COPLEX EQUILIBRIUM BY MEANS OF TRIAL-ITERATION |
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| WANG Qing-Cheng,HE Wen-meng,YIN Guang-fu. EVALUATION ON IONIC DISTRIBUTION FOR THE COMPICATED COPLEX EQUILIBRIUM BY MEANS OF TRIAL-ITERATION[J]. Journal of Sichuan University (Natural Science Edition), 2000, 34(6): 906-910 |
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| Authors: | WANG Qing-Cheng HE Wen-meng YIN Guang-fu |
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| Abstract: | When ligand quantity in the complicated complex equilibrium is not surplus, the ionic distribution to be evaluated is very difficult by classical iteration, but it is not difficult by use of trial-iteration. The method is as follows: from permissible value of thousands and thousands group's of ionic concentration, a number of group of satisfiable trial formula is chosen by trial means, then correcting a group of ionic distribution is confirmed by means of iteration. |
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| Keywords: | trial-iterative mean complex equilibrium ionic distribution not surplus quantityof ligand evaluation |
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