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Na2WO4固—固相变贮热性能的测定
引用本文:刘华亭,武克忠. Na2WO4固—固相变贮热性能的测定[J]. 信阳师范学院学报(自然科学版), 2001, 14(2): 184-185
作者姓名:刘华亭  武克忠
作者单位:河北师范大学化学系,河北石家张,050016
基金项目:河北省教委专项资助项目(97116)
摘    要:利用DTA-TG热分析技术研究了无机塑晶材料Na2WO4的热性能。实验数据表明,Na2WO4的固-固相变焓总和为164.1J/g,是一种有前途的固-固相变贮能材料。固-固相变的机理是随着温度的升高,Na2WO4晶体的晶格发生畸变,晶型由低对称的晶系向高对称的晶系转变,同时引入振动和转动无序,从而吸收热量。

关 键 词:Na2WO4 固-固相变 DTA方法 贮能材料 钨酸钠 贮热性能 测定
文章编号:1003-0972(2001)02-0184-02

Determination of properties of thermal energy storage of Na2WO4 for solid-solid phase transition
LIU Hua ting,WU Ke zhong. Determination of properties of thermal energy storage of Na2WO4 for solid-solid phase transition[J]. Journal of Xinyang Teachers College(Natural Science Edition), 2001, 14(2): 184-185
Authors:LIU Hua ting  WU Ke zhong
Abstract:The thermal properties for the inorganic plastic crystals Na 2WO 4 were investigated by using DTA TG technique.The results obtained showed that the total enthalpy change in the solid solid phase change of Na 2WO 4 is 164.1 J/g.These indicate that Na 2WO 4 has good prospect.The mechnism of sdid sdid phase change is that the structure of Na 2WO 4 crystal changed low symmetry into high symmetry with the increasing of temperature,meanwhile,vibration and rotation become disorderly and absorb heat.
Keywords:Na 2WO 4  solid solid phase change  DTA method  thermal storage materials
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