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Synthesis and ion-binding studies of platinum(II) phenanthroline complexes containing crown ether moiety
摘    要:Square-planar platinum(II) polypyridyl complexes represent an important class of compounds that possess a rich range of spectroscopic and photophysical proper- ties1―17]. Some of them have demonstrated promise in wide-ranging applications including opti…

收稿时间:20 December 2005
修稿时间:6 February 2006

Synthesis and ion-binding studies of platinum(II) phenanthroline complexes containing crown ether moiety
Authors:HAN Xue  WU Lizhu  ZHANG Liping  TUNG Chenho
Institution:(1) Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100101, China
Abstract:Two new benzo-15]-crown-5 attached phenanthroline platinum(II) complexes with the general formula Pt(phen)X2, where X = Cl (1), C≡CC6H5 (2) have been synthesized, and their absorption and luminescence response towards metal ions have been studied.
Keywords:phenanthroline platinum(II) complex  MLCT excited state  benzo-[15]-crown-5 phenanthroline  
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