Synthesis and ion-binding studies of platinum(II) phenanthroline complexes containing crown ether moiety |
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摘 要: | Square-planar platinum(II) polypyridyl complexes represent an important class of compounds that possess a rich range of spectroscopic and photophysical proper- ties1―17]. Some of them have demonstrated promise in wide-ranging applications including opti…
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收稿时间: | 20 December 2005 |
修稿时间: | 6 February 2006 |
Synthesis and ion-binding studies of platinum(II) phenanthroline complexes containing crown ether moiety |
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Authors: | HAN Xue WU Lizhu ZHANG Liping TUNG Chenho |
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Institution: | (1) Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100101, China |
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Abstract: | Two new benzo-15]-crown-5 attached phenanthroline platinum(II) complexes with the general formula Pt(phen)X2, where X = Cl (1), C≡CC6H5 (2) have been synthesized, and their absorption and luminescence response towards metal ions have been studied. |
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Keywords: | phenanthroline platinum(II) complex MLCT excited state benzo-[15]-crown-5 phenanthroline |
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