| 高浓度吡虫啉农药废水催化湿式氧化催化剂 |
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| 引用本文： | 赵彬侠,韩玉英,张小里,李红亚,金奇庭.高浓度吡虫啉农药废水催化湿式氧化催化剂[J].西北大学学报,2005,35(5):585-587,600. |
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| 作者姓名： | 赵彬侠 韩玉英 张小里 李红亚 金奇庭 |
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| 作者单位： | [1]西北大学化工学院,陕西西安710069 [2]西安建筑科技大学市政与环境工程系,陕西西安710054 |
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| 基金项目： | 陕西省教育厅基金资助项目（04JK235）;陕西省自然科学基金资助项目（2004828） |
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| 摘 要： | 目的研究Cu／Ce复合金属氧化物对废水催化氧化程度的影响。方法采用湿式氧化法在2L反应釜中处理吡虫啉农药废水。结果Cu／Ce复合氧化物催化剂对吡虫啉农药废水具有较高的催化活性。结论优化催化剂的设计和制备方法，不但可以提高COD的去除率，而且可有效的降低Cu^2＋和Ce^4＋的溶出量，使该类催化剂具有广阔的使用前景。
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| 关 键 词： | 催化湿式氧化 Cu／Ce复合氧化物催化剂 吡虫啉 共沉淀 |
| 文章编号： | 1000-274X（2005）05-0585-03 |
| 收稿时间： | 2003-10-21 |
| 修稿时间： | 2003-10-21 |
A study on catalysts for catalytic wet oxidation of high concentration imidacloprid pesticide wastewater |
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| ZHAO Bin-xia, HAN Yu-ying,ZHANG Xiao-li, LI Hong-ya,JIN Qi-ting.A study on catalysts for catalytic wet oxidation of high concentration imidacloprid pesticide wastewater[J].Journal of Northwest University(Natural Science Edition),2005,35(5):585-587,600. |
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| Authors: | ZHAO Bin-xia HAN Yu-ying ZHANG Xiao-li LI Hong-ya JIN Qi-ting |
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| Abstract: | Aim To affect COD removal efficiency of wastewater by using copper and cerium oxide catalysts.MethodsThe catalytic wet air oxidation of imidacloprid pesticide wastewater were studied in the 2L autoclave.ResultsThe activity of copper and cerium oxide catalysts were better than that of copper nitrate or cerium nitrate.Conclusion Some measures of controlling the leaching of Cu~(2+) and Ce~(4+),changing the reaction condition and optimizing the design and make of catalysts were discussed.The catalysts would have wide application prospect if the leaching could be controlled. |
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| Keywords: | catalytic wet oxidation multiple oxide of copper and cerium imidacloprid co-precipitation |
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