| 二维层状结构磷酸锌化合物的水热合成与结构表征 |
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| 引用本文： | 王禹,叶俊伟,王莉,关莉,范勇,史苏华.二维层状结构磷酸锌化合物的水热合成与结构表征[J].吉林大学学报(理学版),2006,44(2):291-294. |
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| 作者姓名： | 王禹 叶俊伟 王莉 关莉 范勇 史苏华 |
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| 作者单位： | 吉林大学,化学学院,长春,130012;吉林大学,环境与资源学院,长春,130061 |
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| 摘 要： | 在水热条件下, 制得了ZnHPO4单晶. 对其进行了粉末X射线衍射分析、 红外光谱、 元素分析和单晶X射线衍射分析. 单晶结构分析结果表明, 该晶体属于单斜晶系, P2(1)/c空间群, a=0.462 51(14) nm,b=1.360 8(4) nm, c=0.582 84(18) nm, β=98.752(5)°, V=0.362 56(19) nm3, Z=2， M＝161.35， R1＝0.074 2， wR2＝0.229 6.
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| 关 键 词： | 水热合成 磷酸锌 晶体结构 |
| 文章编号： | 1671-5489(2006)02-0291-04 |
| 收稿时间： | 2005-04-08 |
| 修稿时间： | 2005年4月8日 |
Hydrothermal Synthesis, Crystal Structure and Characterization of a Two-dimensional Layered Zinc Phosphate |
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| WANG Yu,YE Jun-wei,WANG Li,GUAN Li,FAN Yong,SHI Su-hua.Hydrothermal Synthesis, Crystal Structure and Characterization of a Two-dimensional Layered Zinc Phosphate[J].Journal of Jilin University: Sci Ed,2006,44(2):291-294. |
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| Authors: | WANG Yu YE Jun-wei WANG Li GUAN Li FAN Yong SHI Su-hua |
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| Institution: | (1. College of Chemistry， Jilin University， Changchun 130012， China; 2. College of Environment and Resources， Jilin University， Changchun 130061， China) |
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| Abstract: | A new two-dimensional layered zinc phosphate (ZnHPO4) was synthesized by means of hydrothermal method. The as-synthesized product was characterized by means of powder X-ray diffraction and IR spectroscopy. Single-crystal X-ray diffraction analysis shows that the title compound crystallized in the monoclinic space group P2(1)/c (No.14), with the parameters a=0.462 51(14) nm, b=1.360 8(4) nm, c=0.582 84(18) nm, β=98.752(5)°, V=0.362 56(19) nm3, Z=2, M＝161.35， R1＝0.074 2， wR2＝0.229 6. Its structure was built up by infinite four-remembered ring chains sharing vertices, generating a new two-dimensional layer structure. |
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| Keywords: | hydrothermal synthesis zinc phosphate crystal structure |
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