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Effects of Fe content on the microstructure and properties of CuNi10FeMn1 alloy tubes fabricated by HCCM horizontal continuous casting
Authors:Yan-bin Jiang  Jun Xu  Xin-hua Liu  Jian-xin Xie
Institution:Key Laboratory for Advanced Materials Processing of the Ministry of Education, University of Science and Technology Beijing, Beijing 100083
Abstract:Heating-cooling combined mold (HCCM) horizontal continuous casting technology developed by our research group was used to produce high axial columnar-grained CuNi10FeMn1 alloy tubes with different Fe contents. The effects of Fe content (1.08wt%–2.01wt%) on the microstructure, segregation, and flushing corrosion resistance in simulated flowing seawater as well as the mechanical properties of the alloy tubes were investigated. The results show that when the Fe content is increased from 1.08wt%to 2.01wt%, the segregation degree of Ni and Fe elements increases, and the segregation coefficient of Ni and Fe elements falls from 0.92 to 0.70 and from 0.92 to 0.63, respectively. With increasing Fe content, the corrosion rate of the alloy decreases initially and then increases. When the Fe content is 1.83wt%, the corro-sion rate approaches the minimum and dense, less-defect corrosion films, which contain rich Ni and Fe elements, form on the surface of the alloy;these films effectively protect theα-matrix and reduce the corrosion rate. When the Fe content is increased from 1.08wt%to 2.01wt%, the tensile strength of the alloy tube increases from 204 MPa to 236 MPa, while the elongation to failure changes slightly about 46%, indi-cating the excellent workability of the CuNi10FeMn1 alloy tubes.
Keywords:copper nickel alloys  iron content  casting  segregation  mechanical properties  corrosion resistance
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