| 氢化诺卜基腈及其衍生物的合成与结构表征 |
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| 引用本文： | 刘显亮.氢化诺卜基腈及其衍生物的合成与结构表征[J].江西师范大学学报(自然科学版),2016,40(6):566-568. |
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| 作者姓名： | 刘显亮 |
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| 作者单位： | 江西师范大学学报杂志社,江西 南昌 330022 |
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| 摘 要： | 由氢化诺卜基溴在乙醇中与氰化钠回流反应,合成了氢化诺卜基腈,得率达90%以上.后者经水解制得氢化诺卜基甲酸,乙醇解得氢化诺卜基甲酸乙酯,经催化氢化制得了氢化诺卜基甲基胺.各产物经纯化后进行了红外光谱、核磁共振和质谱分析,表征了它们的结构.
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| 关 键 词： | 氢化诺卜基溴 氢化诺卜基腈 衍生物 合成 结构分析 |
The Synthesis and Structural Characterization of Hydronopyl Nitrile and Its Derivatives |
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| LIU Xianliang.The Synthesis and Structural Characterization of Hydronopyl Nitrile and Its Derivatives[J].Journal of Jiangxi Normal University (Natural Sciences Edition),2016,40(6):566-568. |
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| Authors: | LIU Xianliang |
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| Institution: | Periodical Office of Journal,Jiangxi Normal University,Nanchang Jiangxi 330022,China |
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| Abstract: | Hydronopyl nitrile was synthesized from hydronopyl bromid after refluxing in ethanol with sodium cyanide,resulting in a productivity of over 90%.It was further processed into hydronopyl formic acid by hydrolyzation,hydronopyl formate by ethanolysis and hydronopyl methylamine by catalytic hydrogenation.All the products,after purified,were analyzed by IR,NMR and mass spectrum for structural confirmation. |
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| Keywords: | hydronopyl bromid hydronopyl nitrile derivatives systhesis structural analysis |
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