缩聚反应的小分子驱动及其热力学意义

研究了缩合聚合反应封闭体系的平衡过程和开放体系的平衡移动,研究了小分子放出对平衡移动的驱动作用,探讨了这种驱动作用的热力学意义,提出了自由能守恒的概念.认为抽出小分子是一种独立的驱动作用,是质量最低原理的体现.它与能量最低原理(焓减)和熵增原理一起决定自然过程的发展方向.

Small Molecular Motivation to Condensation Polymerization and Its Thermodynamic Significance

In this paper the equilibrium process of closed system and the equilibrium move of opened system in condensation polymerization were investigated. The small molecular motivation to condensation polymerization equilibrium move and its thermodynamic significance were also studied. The concept of conservation of free energy was prepased. The small molecular motivation to condensation polymerization equilibrium move was considered to be a independent motivation and to be suitable to the principle of the lowest mass,the lowest mass principle,the lowest engrgy principle and the entropy inscrease principe decide the developing direction of nature process.