| 2,8,14,20-四异丁基-邻苯三酚杯[4]芳烃的合成及结构 |
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| 引用本文： | 王文逸,胡瑞祥,张红萍,张漫波.2,8,14,20-四异丁基-邻苯三酚杯[4]芳烃的合成及结构[J].湖南师范大学自然科学学报,2012(1):52-55. |
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| 作者姓名： | 王文逸 胡瑞祥 张红萍 张漫波 |
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| 作者单位： | 湖南师范大学化学化工学院;邵阳学院生物与化学工程系 |
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| 基金项目： | 国家自然科学基金资助项目(20871046);湖南省教育厅基金资助项目(11B077);湖南师范大学优秀人才培养计划资助项目(ET20903) |
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| 摘 要： | 杯芳烃是一种具有独特空穴结构和良好性能的大环超分子主体化合物,在超分子材料、离子传感器等研究领域具有广泛应用.以邻苯三酚、异戊醛为原料合成了2,8,14,20-四异丁基-邻苯三酚杯4]芳烃.运用红外光谱,核磁共振氢谱、碳谱以及X-射线单晶衍射对其结构进行了表征.
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| 关 键 词： | 邻苯三酚杯[4]芳烃 晶体 结构 |
Synthesis and Structure of 2,8,14,20-Tetra-Iso-Butyl-Pyrogallol[4] Arene |
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| WANG Wen-yi,HU Rui-xiang,ZHANG Hong-ping,ZHANG Man-bo.Synthesis and Structure of 2,8,14,20-Tetra-Iso-Butyl-Pyrogallol[4] Arene[J].Journal of Natural Science of Hunan Normal University,2012(1):52-55. |
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| Authors: | WANG Wen-yi HU Rui-xiang ZHANG Hong-ping ZHANG Man-bo |
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| Institution: | 1(1.Chemistry and Chemicals College of Hunan Normal University,Changsha 410081,China; 2.Department of Biology and Chemistry Engineering,Shaoyang Universtiy,Shaoyang 422000,China) |
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| Abstract: | Calixarenes,macrocyclic compounds with interior cavity and remarkable property,have been widely used in many research fields,such as supramolecular materials and ion transducer.By using pyrogallol and isovaleraldehyde as raw materials,2,8,14,20-tetra-iso-butyl-pyrogallol4]arene was successfully prepared.The structure of the product was confirmed by IR,1H NMR,13C NMR and single crystal X-ray analysis. |
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| Keywords: | pyrogallol[4]arene crystal structure |
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