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衣康酸/AMPS共聚物作为油井水泥缓凝剂的研究
引用本文:齐志刚,王瑞和,徐依吉,步玉环.衣康酸/AMPS共聚物作为油井水泥缓凝剂的研究[J].北京化工大学学报(自然科学版),2007,34(Z2):32-35.
作者姓名:齐志刚  王瑞和  徐依吉  步玉环
作者单位:中国石油大学石油工程学院,山东 东营 257061
基金项目:中国石油天然气集团公司资助项目
摘    要:以2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为主原料,与衣康酸(IA)在引发剂作用下进行共聚合反应,得到了IA/AMPS共聚物。实验考察了反应条件对产物性能的影响,确定出最佳合成方案;探讨了缓凝剂作用机理,采用IR研究了共聚物的结构。结果表明:单体配比、引发剂用量、反应温度对产物的缓凝性能有很大影响,三者之间存在最佳值。合成的共聚物对水泥浆有优异的缓凝性能,能显著延长水泥浆的稠化时间,并对水泥浆具有良好的分散减阻作用,能够广泛应用油田固井水泥浆体系。

关 键 词:衣康酸  2-丙烯酰胺基-2-甲基丙磺酸  共聚物  合成  缓凝剂  衣康酸  AMPS  共聚物  油井水泥缓凝剂  研究  acid  retarder  cement  oil  well  固井水泥浆体系  油田  应用  减阻  稠化时间  延长  存在  缓凝性能  反应温度  用量  单体配比
修稿时间:2007年7月4日

Itaconic acid/2-acrylamido-2-methlpropanesulfonic acid (AMPS)copolymer as an oil well cement retarder
QI ZhiGang,WANG RuiHe,XU YiJi,BU YuHuan.Itaconic acid/2-acrylamido-2-methlpropanesulfonic acid (AMPS)copolymer as an oil well cement retarder[J].Journal of Beijing University of Chemical Technology,2007,34(Z2):32-35.
Authors:QI ZhiGang  WANG RuiHe  XU YiJi  BU YuHuan
Institution:College of Petroleum Engineering,China University of Petroleum,Dongying Shandong 257061,China
Abstract:A copolymer has been prepared from 2-acrylamido-2-methylpropanesulfonic acid (AMPS) as the major component and itaconic acid as the minor component using an initiatior.The optimum reaction conditions were determined and the mechanism of reaction investigated.The structure of the coolymer was studied by IR spectroscopy.It was found that the properties of the polymer showed a significant variation with monomer ratio,amount of initiatior and reaction temperature,and the optimum combination of these were derived.Addition of the copolymer afforded a significant retardation in the thickening time of a cement slurry and it also had excellent dispersal and drag reducing properties and thus has the potential to be widely applied in oil well cementation.
Keywords:itaconic acid  2-acrylamido-2-methylpropanesulfonic acid  copolymer  synthesis  retarder
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