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RuO_2电极的SEM和AFS研究
引用本文:崔成强,姚士冰,王水菊,周绍民.RuO_2电极的SEM和AFS研究[J].厦门大学学报(自然科学版),1989(5).
作者姓名:崔成强  姚士冰  王水菊  周绍民
作者单位:厦门大学化学系物理化学研究所 (崔成强,姚士冰),厦门大学分析测试中心 (王水菊),厦门大学化学系物理化学研究所(周绍民)
摘    要:通过对 RuO_2电极在不同烧结温度和电解时间条件下表面形貌的观察与 AES分析,推断出RuO_2 电极的活性中心是氧结构空位,在电极表面凸处氧结构空位较多;随着电解的进行,电极活性降低,氧结构空位减少,但在凸处的比在凹处的减少较多,故认为反应点较多地集中在表面凸处。

关 键 词:Ruo_2电极  Auger  活性中心

SEM and AES Studies of RuO_2 Electrode
Cui Chengqiang Yao Shibing Wang Shuiju Zhou Shaomin.SEM and AES Studies of RuO_2 Electrode[J].Journal of Xiamen University(Natural Science),1989(5).
Authors:Cui Chengqiang Yao Shibing Wang Shuiju Zhou Shaomin
Abstract:RuO2 electrodes prepared at various sintering temperatures andelectrolysed for various electrolytic times are studied by means of SEM and AES methods. The results show that the active sites of RuO2 electrode for oxygen evolution are oxygen-deficient structures which at convex spot is more than that at concave spot. As the activation of RuO2 electrode decreases, oxygen-deficient structures at both convex spot and concave spot decrease But the reactive site is mainly centralized at convex spot.
Keywords:RuO2 electrode  Auger  Active sites
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