| 线型聚苯乙烯支载(4S)-噻唑烷-2-硫酮的合成研究 |
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| 引用本文： | 张吉书,何西平,邓晓云,杨桂春,陈祖兴. 线型聚苯乙烯支载(4S)-噻唑烷-2-硫酮的合成研究[J]. 湖北大学学报(自然科学版), 2012, 34(2): 180-183 |
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| 作者姓名： | 张吉书 何西平 邓晓云 杨桂春 陈祖兴 |
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| 作者单位： | 湖北大学化学化工学院,湖北武汉,430062 |
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| 摘 要： | 以N-Boc-L-酪氨酸乙酯为原料,经5步反应合成了一种新的手性辅助试剂——线型聚苯乙烯支载(4S)噻唑烷2硫酮,总产率为40％,所有产物经IR、1H NMR、13C NMR以及元素分析对其结构进行表征,波谱解析结果与化合物的结构相符.
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| 关 键 词： | 线型聚苯乙烯 支载 噻唑烷-2-硫酮 |
Studies on synthesis of non-cross-linked polystyrene supported ( 4S )-thiazolidine-2-thione |
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| ZHANG Jishu , HE Xiping , DENG Xiaoyun , YANG Guichun , CHEN Zuxing. Studies on synthesis of non-cross-linked polystyrene supported ( 4S )-thiazolidine-2-thione[J]. Journal of Hubei University(Natural Science Edition), 2012, 34(2): 180-183 |
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| Authors: | ZHANG Jishu HE Xiping DENG Xiaoyun YANG Guichun CHEN Zuxing |
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| Affiliation: | (School of Chemistry and Chemical Engineering,Hubei University,Wuhan 430062,China) |
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| Abstract: | A new chiral auxiliary,non-cross-linked polystyrene supported (4S)-thiazolidine-2-thione was synthesized using N-Boc-L-tyrosine ethyl ester as initiating material by five steps in 40% overall yield.All the products were characterized by IR,1H NMR,13C NMR.The spectrum results were consistent with the molecular structure. |
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| Keywords: | non-cross-linked polystyrene supported thiazolidine-2-thione |
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