| 固液相转移催化合成活性环丙烷化合物 |
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| 引用本文： | 陈维誉,吴传炎.固液相转移催化合成活性环丙烷化合物[J].河北科技大学学报,1996(2). |
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| 作者姓名： | 陈维誉 吴传炎 |
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| 作者单位： | 河北师范大学化学系，河北轻化工学院校办产业管理处 |
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| 摘 要： | 以氟化钾浸渍的氧化铝为强碱，在固液相转移催化条件下，由活泼亚甲基化合物（１ａ～１ｄ）与１，２－二溴乙烷合成了４种活性环丙烷化合物２ａ～２ｄ，并探讨了其反应机理。
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| 关 键 词： | 相转移催化 烷基化反应 氟化钾 活性环丙烷化合物 |
Synthesis of Active Cyclopropane Compounds under Solid-liquid Phase Transfer Catalysis |
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| Chen Weiyu, Wu Chuanyan.Synthesis of Active Cyclopropane Compounds under Solid-liquid Phase Transfer Catalysis[J].Journal of Hebei University of Science and Technology,1996(2). |
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| Authors: | Chen Weiyu Wu Chuanyan |
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| Abstract: | Four active cyclopropane compounds 2a - 2d were synthesized using active methylene (1a - 1d) and 1, 2-dibromoethane with potassium fluoride soaking alumina as a strong base under the condition of solid-liquid phase transfer catalysis, and the reaction mechanism was discussed in this paper. |
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| Keywords: | phase transfer catalysis alkylation reaction potassium fluoride active cyclopropane compound |
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