| [LM(Cl)_2MCl_2]和[LM(Cl)_2ML'']~(2+)型异核配合物合成及其红外,远红外光谱的研究(L=dpe、bipy;M=Ni、Co、Cu、Zn、Cd、Hg) |
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| 引用本文： | 黄兆华,林立,林永寿. [LM(Cl)_2MCl_2]和[LM(Cl)_2ML'']~(2+)型异核配合物合成及其红外,远红外光谱的研究(L=dpe、bipy;M=Ni、Co、Cu、Zn、Cd、Hg)[J]. 福州大学学报(自然科学版), 1989, 0(3): 79-83 |
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| 作者姓名： | 黄兆华 林立 林永寿 |
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| 作者单位： | 福州大学化学系(黄兆华，林立)，福州大学化学系(林永寿) |
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| 摘 要： | 两种不同含卤配体金属有机化合物，可通过卤原子相联成［ＬＭ（Ｃｌ）２Ｍ‘Ｃｌ２］和［ＬＭ（Ｃｌ）２·Ｍ’Ｌ‘］２＋卤桥型异核配合物．对它们３８００～８０ｃｍ－１间的红外光谱作了研究，并提出构型的设想．
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| 关 键 词： | 卤桥联 异核配合物 |
Preparation for and I.R. Spectra and Raman Spectra of [LM(Cl)_2M''Cl_2] and [LM(Cl)_2M''L'']~(2+) Type Bi-heteronuclear Complexes (L=dpe, bipy; M=Ni, Co, Zn, Cd, Hg) |
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| Huang Zhaohua Lin Li Lin Yongshou. Preparation for and I.R. Spectra and Raman Spectra of [LM(Cl)_2M''Cl_2] and [LM(Cl)_2M''L'']~(2+) Type Bi-heteronuclear Complexes (L=dpe, bipy; M=Ni, Co, Zn, Cd, Hg)[J]. Journal of Fuzhou University(Natural Science Edition), 1989, 0(3): 79-83 |
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| Authors: | Huang Zhaohua Lin Li Lin Yongshou |
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| Affiliation: | Department of Chemstry |
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| Abstract: | Two organometallic comcounds with different metals,which contained halogen atoms as ligand, can combine together by a halide-bridge to form the [LM(Cl)2M'Cl2] and [LM(Cl)2MI L']2+ type bi-heteronuclear complexes. Their I. R. and Raman spectra have been investigated between 3800--80cm-1. Their poss- ible structure is presumed. |
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| Keywords: | halide-bridge heteronuclear complex |
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