| 离子液体中合成己二酸 |
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| 引用本文： | 姚文惠.离子液体中合成己二酸[J].新乡学院学报(自然科学版),2009,26(1):30-31. |
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| 作者姓名： | 姚文惠 |
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| 作者单位： | 新乡学院,建筑工程系,河南,新乡,453003 |
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| 摘 要： | 在处于室温条件下的离子液体中，以NaW04·2H2O为催化剂，H2O2为氧化剂，用环己酮合成己二酸。讨论了离子液体用量、NaWO4·2H2O用量、H2O2用量以及回收离子液体的使用等条件对反应的影响。此法后处理简便，产品收率高（70．5％）。
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| 关 键 词： | 离子液体 己二酸 环己酮 NaWO4.2H2O 30%H2O2 |
Synthesis of Adipic Acid in Ionic Liquid |
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| Authors: | YAO Wen-hui |
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| Institution: | YAO Wen-hui (Dept. of Architectural Engineering, Xinxiang University, Xinxiang 453003, China) |
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| Abstract: | In room temperature ionic liquid, adipic acid was synthesized by oxidation of cyelohexanone. In this reaction 30% hydrogen peroxide was used as oxidant and NaWO4 · 2H2O as catalyst. Through an effort to optimize the reaction conditions, such as the reused ionic liquid, the amount of 30% hydrogen peroxide, NaWO4 · 2 H2O and the ionic liquid, we obtained the best result. This method has the advantage of being a green process along with mild reaction conditions and excellent yields （70.5 %）. |
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| Keywords: | ionic liquid adipic acid cyclohexanol tungsten trioxide 30% of hydrogen peroxide |
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