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壳聚糖接枝丙烯酰胺—聚丙烯酸对Hg(II)的吸附研究
引用本文:徐浩龙.壳聚糖接枝丙烯酰胺—聚丙烯酸对Hg(II)的吸附研究[J].科学技术与工程,2012,12(15):3797-3800.
作者姓名:徐浩龙
作者单位:渭南师范学院化学与生命科学学院;陕西省多河流湿地生态环境重点实验室,渭南714000
基金项目:陕西省教育厅专项科研项目(2010JK544);渭南师范学院专项科研项目(07YKZ031;10YKF011)
摘    要:以过硫酸铵为引发剂,戊二醛、N,N’-亚甲基双丙烯酰胺为交联剂,采用水溶液聚合法使壳聚糖与丙烯酰胺、丙烯酸进行接枝共聚。制备了一种新型壳聚糖接枝丙烯酰胺-聚丙烯酸吸附材料并应用于Hg(Ⅱ)的吸附研究,考察了原料配比、pH、溶液浓度、吸附时间对吸附性能的影响。结果表明:丙烯酸质量分数为25%、pH=5、吸附时间为200 min时,复合材料表现出最佳吸附性能。

关 键 词:壳聚糖  丙烯酰胺  丙烯酸  吸附材料  Hg(Ⅱ)
收稿时间:3/4/2012 10:45:41 AM
修稿时间:3/4/2012 10:45:41 AM

Studies on the Adsorption Properties of Chitosan Graft Acrylamide/Polacrylamide for Hg(II)
Xu Hao-Long.Studies on the Adsorption Properties of Chitosan Graft Acrylamide/Polacrylamide for Hg(II)[J].Science Technology and Engineering,2012,12(15):3797-3800.
Authors:Xu Hao-Long
Institution:XU Hao-long(College of Chemistry and Life Sciences,Weinan Nornal University; Key Laboratory for Eco-environment of Multi-River Wetlands in Shaanxi Province,Weinan 714000,P.R.China)
Abstract:A new absorbent material was prepared from chitosan, acrylamide and acrylic acid by cross-linking reaction and solution polymerization, using ammonium persulfate as the intiator and glutaradehyde and N,N'-methylenebisacrylamide as the cross-linking agent. Its adsorptive property to adsorb toxic Hg(II) ions was studied. When the mass fraction of acrylic acid was 25%, pH=5 and adsorption time 200min, the adsorption behavior of Hg2 was better.
Keywords:chitosan  acrylamide  acrylic acid  Hg(II)  adsorption
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