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下转换发光粉Y2O3/Sm3+在染料敏化太阳能电池中的应用
引用本文:王江丽,林建明,吴季怀,兰章,范乐庆,黄韵防,唐子颖. 下转换发光粉Y2O3/Sm3+在染料敏化太阳能电池中的应用[J]. 厦门大学学报(自然科学版), 2011, 50(Z1): 98-101
作者姓名:王江丽  林建明  吴季怀  兰章  范乐庆  黄韵防  唐子颖
作者单位:华侨大学 材料物理化学研究所,环境友好功能材料教育部工程中心,福建 泉州 362021
基金项目:国家高技术研究发展计划(863)项目,国家自然科学基金
摘    要:采用沉淀法制备了Y2O3/Sm3+下转换发光粉,利用X射线衍射、荧光光谱对其进行了表征,并利用该发光粉具有下转换发光的特点将其应用于染料敏化太阳能电池(DSSC).结果表明,Y2O3/Sm3+下转换发光粉可以增加电池对太阳光的吸收范围,提高电池的光电流和光电压.研究了掺杂量对电池性能的影响,当掺杂量为3%时,光电转换效率从5.049%提高到5.94%,表明了其是一种有效提高光电转换效率的方法.

关 键 词:染料敏化太阳能电池  稀土离子  下转换发光粉  p-型掺杂

The Application of Down-conversion Luminescent powder Y2O3/Sm3+ in Dye-sensitized Solar Cells
WANG Jiang-li,LIN Jian-ming,WU Ji-huai,LAN Zhang,FAN Le-qing,HUANG Yun-fang,TANG Zi-ying. The Application of Down-conversion Luminescent powder Y2O3/Sm3+ in Dye-sensitized Solar Cells[J]. Journal of Xiamen University(Natural Science), 2011, 50(Z1): 98-101
Authors:WANG Jiang-li  LIN Jian-ming  WU Ji-huai  LAN Zhang  FAN Le-qing  HUANG Yun-fang  TANG Zi-ying
Affiliation:WANG Jiang-li,LIN Jian-ming,WU Ji-huai,LAN Zhang,FAN Le-qing,HUANG Yun-fang,TANG Zi-ying(Engineering Research Center of Environment-Friendly Functional Materials,Ministry of Education,Institute of Materials Physical Chemistry,Huaqiao University,Quanzhou 362021,China)
Abstract:Y2O3/Sm3+ down-conversion luminescent powder was synthesized by a method of precipitation,its structure was characterized by X-ray diffraction.Also,its excitation and emission spectra were presented.Owing to the character of down-conversion,Y2O3/Sm3+ down-conversion luminescent powder was introduced into TiO2 film in dye-sensitized solar cell(DSSC).As a luminescence medium,Y2O3/Sm3+ down-conversion luminescent improves the light harvesting via a conversion luminescence process and increases the photocurrent...
Keywords:dye-sensitized solar cell  rare earth ion  down-conversion luminescent powder  p-type doping  
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