| Cu(PPh3)nX(n=1,3;X=Cl,Br,I)的直接电化学合成 |
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| 引用本文： | 齐莹莹,修福荣,顾建胜. Cu(PPh3)nX(n=1,3;X=Cl,Br,I)的直接电化学合成[J]. 漳州师范学院学报, 2006, 18(2): 50-52 |
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| 作者姓名： | 齐莹莹 修福荣 顾建胜 |
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| 作者单位： | [1]漳州师范学院化学系,福建漳州363000 [2]苏州大学化学化工学院,江苏苏州215006 |
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| 摘 要： | 以固体NH4X和I2为原料，在非水溶剂中一步电合成得到Cu（PPh3）nX系列配合物，考察了不同原料配比对产物的影响．在最佳合成条件下，配合物的产率均在95％以上．同时讨论了电合成机理．
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| 关 键 词： | 配合物 三苯基膦 电合成 |
| 文章编号： | 1008-7826（2006）02-0050-03 |
| 收稿时间： | 2006-02-12 |
| 修稿时间： | 2006-02-12 |
Electrochemical Preparation of Cu(PPh3)nX(n=1,3; X=Cl,Br,I) |
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| QI Ying-ying,XIU Fu-rong,GU Jian-sheng. Electrochemical Preparation of Cu(PPh3)nX(n=1,3; X=Cl,Br,I)[J]. Journal of ZhangZhou Teachers College(Natural Science), 2006, 18(2): 50-52 |
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| Authors: | QI Ying-ying XIU Fu-rong GU Jian-sheng |
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| Affiliation: | Department of chemistry, Zhangzhou Normal University, Zhangzhou, Fujian 363000, China; Department of chemistry, Suzhou University, Suzhou, Jiangsu 215006, China |
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| Abstract: | Some complexs of Cu(PPh3)nX(n=1,3;X=C1,Br,I) were electrosynthe-sized using NH4X or I2 in non-aqueous medium,in yield >95%.The mechanism of electrochemical reaction and the effect of material ratio on the complexs have been studied.When n(PPh3)?n(NH4X)=1?1,Cu(PPh3)X(X=Cl,Br,I) were ob-tained;when n(PPh3)?n(NH4X)=3?1,Cu(PPh3)3X(X=Cl,Br,I) were obtained.This method is better than the traditional chemical synthesis. |
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| Keywords: | copper complex triphenylphosphine eleetrosynthesis |
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