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| 多羟基超支化聚(胺-酯)修饰多壁碳纳米管 | |
| 引用本文： | 朱靖,裴占宇,池俊杰,董振华,尹红娜,魏宏亮.多羟基超支化聚(胺-酯)修饰多壁碳纳米管[J].河南师范大学学报(自然科学版),2009,37(2). |
| 作者姓名： | 朱靖 裴占宇 池俊杰 董振华 尹红娜 魏宏亮 |
| 作者单位： | 1. 河南工业大学,化学化工学院,郑州,450001 2. 黎明化工研究院,河南,洛阳,471001 3. 河南省商业科学研究所有限责任公司,郑州,450002 |
| 摘 要： | 通过原位酯交换聚合反应,在多壁碳纳米管(MWNTs)表面接枝多羟基超支化聚胺-脂取得成功.分步产物的结构用FTIR进行了表征,TGA确定了修饰类型为共价接枝,SEM观察到MWNTs改性前后的形貌变化,并首次采用化学滴定方法确定了接枝在碳纳米管上的超支化聚合物的平均代数.接枝修饰后的MWNTs在水、乙酸乙酯等常见溶剂中的分散能力明显提高. |
| 关 键 词： | 多壁碳纳米管 超支化聚(胺-酯) 接枝 |
Multihydroxyl Hyperbranched Poly(amine-ester)s Modification of Multiwalled Carbon Nanotubes |
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| ZHU Jing,PEI Zhan-yu,CHI Jun-jie,DONG Zheng-hua,YIN Hong-na,WEI Hong-liang.Multihydroxyl Hyperbranched Poly(amine-ester)s Modification of Multiwalled Carbon Nanotubes[J].Journal of Henan Normal University(Natural Science),2009,37(2). | |
| Authors: | ZHU Jing PEI Zhan-yu CHI Jun-jie DONG Zheng-hua YIN Hong-na WEI Hong-liang |
| Institution: | 1.School of Chemistry and Chemical Engineering;Henan University of Technology;Zhengzhou 450001;China;2.Liming Research Institute of Chemical Industry;Luoyang 471001;3.The Commercial Science Research LTD.Company of Henan Province;Zhenzhou 450002;China |
| Abstract: | An in situ transesterification polymerization strategy is employed to grow the multihydroxyl hyperbranched poly(amine-ester)s on the surfaces of multiwalled carbon nanotubes(MWNTs).The modified MWNTs of each step are characterized by FTIR,and the kind of modification is confirmed as covalent graft by TGA.The morphologies of the MWNTs before and after grafted are observed by SEM.And the average generation number of hyperbranched poly(amine-ester)s on the surface of MWNTs is measured by titration.The as-prepa... |
| Keywords: | multiwalled carbon nanotubes hyperbranched poly(amine-ester)s graft |
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