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SrCeO3基高温质子导体的制备与性能测定
引用本文:郑敏辉,甄秀欣.SrCeO3基高温质子导体的制备与性能测定[J].北京科技大学学报,1993,15(3):310-315.
作者姓名:郑敏辉  甄秀欣
作者单位:北京科技大学物理化学系 (郑敏辉,甄秀欣),北京科技大学物理化学系(赵志刚)
摘    要:

关 键 词:高温质子导体  助熔剂  SrCeO3基

Preparation and Characterization of Yb Doped SrCeO_3 Based High Temperature Proton Conductor
Zheng Minhui Zhen Xiuxin Zhao Zhigang.Preparation and Characterization of Yb Doped SrCeO_3 Based High Temperature Proton Conductor[J].Journal of University of Science and Technology Beijing,1993,15(3):310-315.
Authors:Zheng Minhui Zhen Xiuxin Zhao Zhigang
Institution:Zheng Minhui Zhen Xiuxin Zhao Zhigang Department of Physical Chemistry
Abstract:Small amount of H3BO3, SrCl2 or SrF2 improved the specific gravity of calcined SrCeO3based powder. The addition of 2% SrF2made the specific gravity close to the theoretical. The results of DTA, TG and XRD shown that the addition of fluxes accelerates the formation of SrCeO3. Using the precursor powder, ceramics having density above 94% of the theoratical have been sintered. The measurements of AC impedance and EMF of hydrogen concentration cell shown that the addition of SrF2does not degrade the material properties. The proton transference number is close to unit in the temperature range of 773-973K.
Keywords:proton conductor- flux  improvement of density  thermal analysis  
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