| Keggin结构钛和过氧钛一取代钨硅杂多配合物氧化还原性质的研究 |
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| 引用本文： | 单秋杰,娄华,侯来芳.Keggin结构钛和过氧钛一取代钨硅杂多配合物氧化还原性质的研究[J].高师理科学刊,1997(3). |
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| 作者姓名： | 单秋杰 娄华 侯来芳 |
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| 作者单位： | 齐齐哈尔师范学院化学系(单秋杰)，齐市一中(娄华)，齐齐哈尔第一职业中学(侯来芳) |
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| 摘 要： | 采用电化学方法研究了钛和过氧钛一取代Ｋｅｇｇｉｎ结构杂多配合物α－K_5HSiW_11Tio_46].4H_2O和α,β_i-M_6H_11SiW_11(TiO_39].xH_2O(i=1,2,3) 的氧化还原性质。实验结果表明：Ti-O-O含 配合物中Ｏ_２~(２-)的不可逆还原波出现在－０．１Ｖ左右，由于Ｏ_２~(２－)的存在明显地增强了配合物的氧化还原性能．故过氧杂多配合物可作氧化型催化剂．
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| 关 键 词： | Keein结构 过氧钛杂多配合物 氧化还原性质 |
Study on Redox Property of Titanium and Peroxotitanium mono Substituted Heteropoly-tungstates with Keggin Structure |
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| Shan Qiujie Lou Hua.Study on Redox Property of Titanium and Peroxotitanium mono Substituted Heteropoly-tungstates with Keggin Structure[J].Journal of Science of Teachers＇College and University,1997(3). |
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| Authors: | Shan Qiujie Lou Hua |
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| Institution: | Shan Qiujie Lou Hua (Department of Chemistry) (No. 1 Middle. School of Qiqihar) Hou Laifang (No. 1 Professional Middle School of Qiqihar) |
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| Abstract: | The studies on redox properties of titanium and peroxotitanium mono substiuted heteropoly complexes with Keggin Structure:a-K5HSiW11TiO40)·4H2O, α-,βi--MaHbSiW11(TiO2)O39).xh2O(i= 1, 2, 3) were made by electrochmistry methods. The experiment results indicate that reduced waves of peroxyious are in the range of -0. 1 V.The presence of peroxytitanium increases the oxidation of heteropoly complexes. |
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| Keywords: | Keggin Structure Peroxotitanium heteropdy complex Redox Property |
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