| ［（N，N－二膦酸亚甲墓）甘氨酸－磷酸氢］锆－钯催化剂的催化加氢活性 |
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| 引用本文： | 傅相锴,马学兵,刘昌华,何佑秋,温淑英.［（N，N－二膦酸亚甲墓）甘氨酸－磷酸氢］锆－钯催化剂的催化加氢活性[J].西南师范大学学报(自然科学版),1996(2). |
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| 作者姓名： | 傅相锴 马学兵 刘昌华 何佑秋 温淑英 |
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| 作者单位： | 西南师范大学化学化工学院 |
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| 基金项目： | 国家自然科学基金，中国石化总公司石油化工科学院联合资助 |
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| 摘 要： | 一类新型负载钯催化剂：［（Ｎ，Ｎ－二膦酸亚甲基）甘氨酸－磷酸氢］锆－钯催化剂由Ｚｒ（ＨＰＯ４）２－ｘ［（Ｏ３ＰＣＨ２）２ＮＣＨ２ＣＯ２Ｈ］ｘ·Ｈ２Ｏ与ＰｄＣｌ２在甲醇中络合和水台胼还原制得．研究了催化剂在常压下对取代烯烃和硝基苯的加氢反应，催化剂的ｘ值、Ｐｄ％含量，＞ＮＣＨ２ＣＯ２Ｈ／Ｐｄ比值、反应温度、溶剂和底物对催化加氢活性的影响也进行了研究．催化剂可重复使用８次而无显著失活．［（Ｎ，Ｎ－二膦酸亚甲基）甘氨酸－磷酸氢］锆；氯化钯；负载；催化活性
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Catalytic Activities of Zirconium (Glycine-N,N-dimethylphosphonate)-palladium in Hydrogenation |
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| Fu Xiangkai,Xuebin,He Youqin,Liu Changhua,Wen Shuying.Catalytic Activities of Zirconium (Glycine-N,N-dimethylphosphonate)-palladium in Hydrogenation[J].Journal of Southwest China Normal University(Natural Science),1996(2). |
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| Authors: | Fu Xiangkai Xuebin He Youqin Liu Changhua Wen Shuying |
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| Abstract: | Zirconium(Glycine-N,N-dimethylphosphonate-phosphate-palladium,A new type of suppportedpalladium catalyst was prepared for the first time by complexing of Zr(HPO4)2-x(O3 PCH2)2 NCH2 CO2H]x.H2O with PdCl2 in methanol and being reduced with hydrazine hydrate.The hydrogenation of substituted olefines and nitrobenzene under atmospheric pressure catalyzed by thecatalyst was studied. The infuence of x,Pd%,NCH2CO2H/Pd ratio, reaction temperature,solventsand substrates on the cataytic activitieS in hydrogenation was also discussed.The catalyst can be reused eight times without serious loss of activity. |
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| Keywords: | Zirconium(glycine-N N-dimethylphosphonate-phosphate) palldium chlorid support hydrogenation catalytic activity |
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