关于一价原子谱线精细结构能级修正项的表述与推证

本文依据相对论量子力学理论,对一价原子谱线精细结构能级修正项的某些表述提出不同的看法。另外,着重指出目前通行的对自旋—轨道耦合能的传统推导在概念和逻辑上存在的原则性错误。最后,提出一个新的基本公式,解决了半经典推导过程所发生的困难问题。

Expression of and Reasoning on the Energy Level Correction Term of Fine Structure of One-valence Atomic Spectrum

In this paper,on the basis of quantum mechanics of relativity,the author expresses different views on some expressions of the energy level correction term of fine structure of one-valence atomic spectrum.Furthermore,he emphatically points out that the prevalent conventional deduction from spin-orbit coupling energy is incorrect in principle both conceptionally and logically.Finally,the au- thor puts forward a new basic formula to solve the difficult problems occurring in the course of semi- classical deduction.