The diversity of marine sterols and the role of algal bio-masses; from facts to hypothesis

Summary Modern analytical methods have revealed the great variety of marine sterols, which possess many different side chains and unsaturation patterns. Such biochemical transformations require well-defined mechanistic pathways, and there must be some Raison d'Etre for a situation which has withstood evolution and adaptive changes. However, in this area, insufficient and sometimes not very substantial experimental work has made it difficult to see correlations, and hence to form a solid hypothesis. A review is now presented in which the molecules dissolved in sea water, or found in marine organisms are considered with particular reference to algal production, and to the bio-ecological significance of the main sterols.