| 新型硼酸类荧光化合物的合成及对糖分子的识别性能 |
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| 引用本文： | 吕晓兰,欧阳杰,王秋生,张家祥,孙华东,梁文睿.新型硼酸类荧光化合物的合成及对糖分子的识别性能[J].天津理工大学学报,2011,27(1):60-63,68. |
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| 作者姓名： | 吕晓兰 欧阳杰 王秋生 张家祥 孙华东 梁文睿 |
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| 作者单位： | 大津理工大学化学化工学院,天津,300384 |
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| 基金项目： | 国家自然科学基金，国家自然科学基金，天津市自然科学基金 |
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| 摘 要： | 设计合成了具有苯并咪唑结构的芳硼酸类新型荧光化合物,并进行了结构表征;研究了新化合物的荧光性质;并分别探讨了此类化合物在50%甲醇水溶液中对D-葡萄糖、D-果糖、D-麦芽糖的作用,研究结果表明,合成的目的化合物与单糖和双糖都有较强的作用,使化合物的荧光发生特征性改变,特别是对果糖有很好的选择性识别,此类化合物可作为检测果糖的荧光传感器开展进一步研究.
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| 关 键 词： | 芳硼酸衍生物 荧光传感器 合成 果糖 选择性识别 |
The synthesis of novel fluorescence compounds with boronic acid and its recognition properties of sugar |
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| LV Xiao-lan,OUYANG he,WANG Qiu-sheng,ZHANG Jia-xiang,SUN Hua-dong,LIANG Wen-rui.The synthesis of novel fluorescence compounds with boronic acid and its recognition properties of sugar[J].Journal of Tianjin University of Technology,2011,27(1):60-63,68. |
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| Authors: | LV Xiao-lan OUYANG he WANG Qiu-sheng ZHANG Jia-xiang SUN Hua-dong LIANG Wen-rui |
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| Institution: | LV Xiao-lan,OUYANG Jie,WANG Qiu-sheng,ZHANG Jia-xiang,SUN Hua-dong,LIANG Wen-rui (Shchool of Chemistry and Chemical Engineering,Tianjin University of Technology,Tianjin 300384,China) |
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| Abstract: | In this paper,novel fluorescence compounds with aromatic boronic acid and benzimidazole were synthesized,and their structures and fluorescent properties were measured.The reactions of these compounds with sugars including D-glucose,D-fructose and D-maltose were examined in 50% methanol aqueous.The fluorescent properties of the novel fluorescence compounds binding with mono saccharides or disaccharides were changed.And the results indicate that the compounds have substantial selectivity to fructose.Further r... |
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| Keywords: | aromatic boronic acid derivatives fluorescence sensor synthesis fructose selective identification |
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