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交流示波极谱滴定测定水泥中的Fe_2O_3和Al_2O_3
引用本文:王永红,钟国伦,张桂利,杨春霞. 交流示波极谱滴定测定水泥中的Fe_2O_3和Al_2O_3[J]. 济南大学学报(自然科学版), 1995, 0(3)
作者姓名:王永红  钟国伦  张桂利  杨春霞
作者单位:山东建材学院应用化学系,山东大学化学院
摘    要:研究了在pH=4.3的HAc—NaAc缓冲溶液中,用EDTA滴定水泥熟料中的Fe3+,并以Zn2+的切口消失来指示终点,对Fe3+进行测定,以及在测定了Fe3+的溶液中用Zn2+标液返滴定到出现Zn2+切口指示终点来测定Al3+的交流示波极谱连续测定Fe3+和Al3+的新方法。关键词

关 键 词:交流示波极谱,水泥,二氧化二铁,二氧化二铝

DETERMINATION OF Fe_2O_3 AND Al_2O_3 IN CEMENT WITH AC OSCILLOPOLAROGRAPHIC TITRATION
Wang Yonghong,Zhong Guolun ,Zhang Guili,Yang Chunxia. DETERMINATION OF Fe_2O_3 AND Al_2O_3 IN CEMENT WITH AC OSCILLOPOLAROGRAPHIC TITRATION[J]. Journal of Jinan University(Science & Technology), 1995, 0(3)
Authors:Wang Yonghong  Zhong Guolun   Zhang Guili  Yang Chunxia
Abstract:A new method was developed for determination of Fe_2O_3 and Al_2O_3 in cement.EDTA is used to titrate Fe3+ions in solution of HAc-NaAc (PH= 4. 3). The gap of Zn2+ ions is used to indicate the end-point. The standard solution of Zn2+ is used to indicate the excessive EDTA after it is added to the solution which Fe3+ions has been titrated. The gap of Zn2+ions is also used to indicate the end-point which can caculate the quantity of Al3+.
Keywords:AC oscillopolarography  titration  cement  ferrio oxide and aluminium oxide  
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