| 磺化聚苯硫醚—铑配合物催化的氢甲酰化 |
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| 引用本文： | 吴也凡,洪亮.磺化聚苯硫醚—铑配合物催化的氢甲酰化[J].厦门大学学报(自然科学版),1992,31(3):256-260. |
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| 作者姓名： | 吴也凡 洪亮 |
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| 作者单位： | 厦门大学生物学系
(吴也凡)，厦门大学化学系
(洪亮，林国栋)，厦门大学化学系(袁友珠) |
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| 摘 要： | 光电子能谱对水溶性碘化聚苯硫醚—铑配合物催化剂的测定结果表明,其中铑的价态为Rh~1,以链节/金属摩尔比为5的该配合物为催化剂,在互不相溶的水/有机溶剂二相介质中对十一烯酸甲酯的氯甲酰化反应进行了初步研究,考察了不同的温度、压力、pH值等反应条件对氢甲酰化反应的影响,在P_(H3)为1～3MPa内,随着氢分压的增大,产物的转化率和正异构比都随之增加,水相最佳反应pH值为8。
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| 关 键 词： | 磺化聚苯硫醚 铑 氢甲酰化 配合物 |
Research on the Sulfonated Polyphenylene Sulfide Rhodium Complexes Catalyzed Hydroformylation Reaction |
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| Wu Yefan Hong Lian Ling Guodong Yuan Youzhu.Research on the Sulfonated Polyphenylene Sulfide Rhodium Complexes Catalyzed Hydroformylation Reaction[J].Journal of Xiamen University(Natural Science),1992,31(3):256-260. |
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| Authors: | Wu Yefan Hong Lian Ling Guodong Yuan Youzhu |
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| Institution: | Wu Yefan Hong Lian Ling Guodong Yuan Youzhu (Dept . of Bio. ) (Dept. of Chem. ) |
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| Abstract: | The water-soluble sulfonated polyphenylene sulfide rhodium complexes were vued as catalysts in hydroformylation of methyl w-undecylenoate in liq. -Liq. two immiscible phases system. The effects of different condition were examined on the hydroformylation reaction. |
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| Keywords: | Sulfonated polyphenylene sulfide Rhodium Hydroformylation |
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