Synthese von Solanidin aus Demissidin |
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| Authors: | K. Schreiber H. Rönsch |
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| Affiliation: | (1) Deutsche Akademie der Landwirtschaftswissenschaften zu Berlin, Forschungsstelle Mühlhausen/Thüringen, Deutschland |
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| Abstract: | Summary The steroidal alkaloid solanidine (solanid-5-ene-3 -ol, II) which occurs in the potato plantSolanum tuberosum L. has been synthesized from demissidine (5 -solanidane-3-ol, I), an alkaloid from the Mexican wild potatoSolanum demissum Lindl. The synthesis involves the following steps: 5-solanidane-3-one, 2,4-dibromo-5-solanidane-3-one, solanid-4-ene-3-one, 3-acetoxy-solanida-3,5-diene, and solanidine (II).
Solanum-Alkaloide. XVII. Mitteilung. — XVI. Mitteilung:K. Schreiber undG. Adam, Exper.17, 490 (1961). |
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