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用硫酸铁──硫酸作浸取剂从闪锌矿制备七水合硫酸锌
引用本文:杜宝安,韩鹏,荆妍.用硫酸铁──硫酸作浸取剂从闪锌矿制备七水合硫酸锌[J].河北大学学报(自然科学版),1994(4).
作者姓名:杜宝安  韩鹏  荆妍
作者单位:Department of Chemistry,Hebei University,Baoding 071002
摘    要:本文介绍了用硫酸铁-硫酸作浸取剂,从闪锌矿制备七水硫酸锌的工艺过程。用铁屑作中和剂和还原剂除去浸取液中的酸和未反应的Fe ̄(3+),从溶液中结晶出大部分FeSO_4·7H_2O后,用“针铁矿”法除去剩余的Fe ̄(2+),用四氯乙烯作萃取剂回收渣中的硫。

关 键 词:七水硫酸锌,制备,针铁矿,四氯乙烯

Preparation of Zinc Sulphate Heptahydrate from Blende Using Iron Sulfate and Sulfuric Acid as Extractant
Du Baoan Han Peng Jing Yan.Preparation of Zinc Sulphate Heptahydrate from Blende Using Iron Sulfate and Sulfuric Acid as Extractant[J].Journal of Hebei University (Natural Science Edition),1994(4).
Authors:Du Baoan Han Peng Jing Yan
Abstract:Zinc sulfate heptahydrate was prepared by extraction of blende with ferricsulfate and sulfuric acid as extractant.First the excess acid and unreacted Fe ̄(3+)were trans-ferred to Fe ̄(2+) by iron finngs,then Fe ̄(2+)was removed by“goethite”method after most ofgreen vitriol was crystallized from the solution。For recovery of sulfur in the dregs ethylenetetrachloride was used as extractant.
Keywords:Zinc sulfate heptahydrate Preparation GoethiteEthylene tetrach lo ride  
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