| 聚苯撑乙炔共轭聚合物的合成及光电性能 |
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| 引用本文： | 牛俊峰,杨志祥,黄光荣,曾翎.聚苯撑乙炔共轭聚合物的合成及光电性能[J].浙江科技学院学报,2006,18(2):90-93,98. |
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| 作者姓名： | 牛俊峰 杨志祥 黄光荣 曾翎 |
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| 作者单位： | 浙江科技学院,生物与化学工程学院,杭州,310023 |
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| 基金项目： | 国家自然科学基金;浙江省教育厅优秀青年教师资助项目 |
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| 摘 要： | 利用钯催化剂Pd(PPh3)2Cl2和相转移催化剂PTC,采用Heck交叉偶联缩聚反应合成了(苯撑乙炔-氰基乙烯苯撑)共聚物(C12-PPE-DCNTB),比较了聚合物的紫外吸收光谱和荧光光谱特征及热稳定性。以ITO为阳极,Ba/Al为阴极,制备了构型为ITO/PEDOT-PSS/MEH-PPV C12-PPE-DCNTB(1/1,m/m)/Ba/Al的本体异质结器件,初步讨论了活性层的光物理特征及器件的光伏性能。
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| 关 键 词： | 共轭聚合物 聚苯撑乙炔 氰基乙烯苯撑 光伏性能 |
| 文章编号： | 1671-8798（2006）02-0090-04 |
| 收稿时间： | 03 1 2006 12:00AM |
| 修稿时间： | 2006-03-01 |
Synthesis and Photovoltaic Devices Performance of Poly(phenylene-bisethynylene)-alt-((cyano-styryl)benzene) |
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| NIU Jun-feng,YANG Zhi-xiang,HUANG Guang-rong,ZENG Ling.Synthesis and Photovoltaic Devices Performance of Poly(phenylene-bisethynylene)-alt-((cyano-styryl)benzene)[J].Journal of Zhejiang University of Science and Technology,2006,18(2):90-93,98. |
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| Authors: | NIU Jun-feng YANG Zhi-xiang HUANG Guang-rong ZENG Ling |
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| Institution: | School of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou 310023, China |
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| Abstract: | poly(phenylene-bisethynylene)-alt-((cyano-styryl)benzene) alternating copolymer containing electron donor and electron acceptor units was synthesized by cross-coupling polycondensation with Pd(PPh_3)_2Cl_2 and phase transfer catalysts.The UV-Vis and PL of copolymer were measured respectively.Photovoltaic devices based on the configuration of ITO/PEDOT-PSS/ C12-PPE-DCNTB /Ba/Al were fabricated.The photophysics of active layer,photovoltaic performance of the devices was also discussed. |
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| Keywords: | conjugated polymer poly(phenyleneethynylene) (cyano-styryl)benzene photovoltaic devices |
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