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二氯化一氯五氨合钴(Ⅲ)的制备及组成测定
引用本文:凌必文,张春艳. 二氯化一氯五氨合钴(Ⅲ)的制备及组成测定[J]. 安庆师范学院学报(自然科学版), 2006, 12(1): 86-88
作者姓名:凌必文  张春艳
作者单位:安庆师范学院,化学系,安庆,246011;安庆师范学院,化学系,安庆,246011
摘    要:以氯化钴(Ⅱ)为起始原料,在氨水和氯化铵介质中合成了一种紫红色的配合物,对该配合物的组成进行测定,证实该配合物为二氯化一氯五氨合钴(Ⅲ),其化学式为[Co(NH3)5Cl]Cl2。

关 键 词:二氯化一氯五氨合钴  莫尔法  碘量法  配合物  配体
文章编号:1007-4260(2006)01-0086-03
收稿时间:2005-11-03
修稿时间:2005-11-03

Preparation and Component Determination of Chloro-pen-fammine Cobaltichloride [Co(NH3)5Cl]Cl2
LING Bi-wen,ZHANG Chun-yan. Preparation and Component Determination of Chloro-pen-fammine Cobaltichloride [Co(NH3)5Cl]Cl2[J]. Journal of Anqing Teachers College(Natural Science Edition), 2006, 12(1): 86-88
Authors:LING Bi-wen  ZHANG Chun-yan
Affiliation:School of Chemistry and Environment science, Anqing Teachers College, Anqing 246011 ,China
Abstract:A purplish red crystal of cobalt coordination is synthesized by using cobalt chloride and ammonia chloride on certain condition. The method is simple, and the reaction condition can be controlled easily. In this paper, the complex is determined by some typical methods such as mole ratio method and iodimetry .Its chemical reaction is [Co(NH3)5Cl]Cl2
Keywords:coordination  ligand  Chloro-pen-fammin  coballichloride  mole ratio method  iodimelry.
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