| CH3SH与简单自由基反应的研究现状 |
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| 引用本文： | 樊红敏,曾艳丽,孟令鹏,郑世钧.CH3SH与简单自由基反应的研究现状[J].河北师范大学学报(自然科学版),2004,28(5):500-504. |
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| 作者姓名： | 樊红敏 曾艳丽 孟令鹏 郑世钧 |
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| 作者单位： | 河北师范大学,计算量子化学研究所,河北,石家庄,050091;河北师范大学,计算量子化学研究所,河北,石家庄,050091;河北师范大学,计算量子化学研究所,河北,石家庄,050091;河北师范大学,计算量子化学研究所,河北,石家庄,050091 |
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| 基金项目： | 河北省自然科学基金资助项目(B2004000147) |
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| 摘 要： | 含硫有机化合物在对流层大气化学中起着重要的作用.目前在实验和理论上对CH3SH,CD3SH及CD3SD的反应进行了很多研究,主要集中在CH3SH与原子(O,H,F,Cl,Br等)、双原子分子和双原子自由基(NO,OH,OD,BrO,CN等)、三原子分子和自由基及多原子(O3,NO3等)的反应.本文中,笔者对CH3SH与原子和双原子自由基的反应进行了综述.
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| 关 键 词： | CH3SH 同位素 氢抽提 速率常数 |
| 文章编号： | 1000-5854(2004)05-0500-05 |
| 修稿时间： | 2004年4月1日 |
The Present Studies on the Reaction of CH3SH with Simple Radicals |
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| FAN Hong-min,ZENG Yan-li,MENG Ling-peng,ZHENG Shi-jun.The Present Studies on the Reaction of CH3SH with Simple Radicals[J].Journal of Hebei Normal University,2004,28(5):500-504. |
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| Authors: | FAN Hong-min ZENG Yan-li MENG Ling-peng ZHENG Shi-jun |
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| Abstract: | Organic sulfide compounds play an important role in tropospheric chemistry,a lot of researches have been proceeded on the reaction of CH_3SH,CD_3SH and CD_3SD in experimented and theoretical chemistry recently.The researches focus on the reactions of CH_3SH with some single atoms(O,H,F,Cl,Br etc),some two-atom molecules and radicals (NO,OH,OD,BrO,CN etc),three-atom molecules and radicals (O_3,NO_3 etc) and many-atoms molecules and radicals.Some reactions of CH_3SH with single atoms and two-atom radicals were reviewed. |
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| Keywords: | CH_3SH isotope hydrogen atom abstraction rate constant |
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