| 氯代十八烷的合成及表征 |
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| 引用本文： | 贾勇,鲁传华,赵贤普.氯代十八烷的合成及表征[J].安徽大学学报(自然科学版),2004,28(5):61-64. |
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| 作者姓名： | 贾勇 鲁传华 赵贤普 |
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| 作者单位： | 安徽中医学院,药学院,安徽,合肥,230038;安徽中医学院,药学院,安徽,合肥,230038;安徽中医学院,药学院,安徽,合肥,230038 |
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| 摘 要： | 以SOCl2为氯化试剂在吡啶的催化下与十八醇反应合成了氯代十八烷,产物用傅立叶变换红外光谱进行了表征,并测定产物的熔点与含量。对文献报道的方法进行改进,用过量的SOCl2为溶剂使反应在均相溶液中进行,条件温和;对合成工艺及条件进行了讨论,给出反应物最佳的用量比例、适宜的温度范围与反应时间,获得了88.6%-92.1%的产率。
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| 关 键 词： | 氯代十八烷 合成 表征 |
| 文章编号： | 1000-2162(2004)05-0061-04 |
Synthesis and characterization of n-chlorinated octadecane |
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| JIA Yong,LU Chuan-hua,ZHAO Xian-pu.Synthesis and characterization of n-chlorinated octadecane[J].Journal of Anhui University(Natural Sciences),2004,28(5):61-64. |
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| Authors: | JIA Yong LU Chuan-hua ZHAO Xian-pu |
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| Abstract: | In this paper, n-chlorinated octadecane was synthesized by means of using thionyl chloride as chlorination agent and solvent. Its structure was characterized by using FT-IR. The synthetic technique was improved to attain 88.6-92.1% yield. The synthetic conditions were discussed and the optimum conditions were given. |
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| Keywords: | chlorinated octadecane synthesis token |
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