基元可逆反应亲合势衰减常数Ar的讨论

Garfinkle发现,可逆反应亲合势的时间变化率和时间的倒数存在着近似的线性关系。将亲合势函数和动力学方程结合起来对这发现分析,就可以得出:这种线性关系之所以存在,从数学上说,是因为亲合势的时间变化率函数,当以时间的倒数为自变量,且t~(-1)→∞时,存在着渐近线;对同一类型的基元反应,渐近线的斜率是个定值,渐近线截距的正负性是确定的,和具体的动力学数据无关。

Discussion on Constants A, of Chemical Affinity Decay of Elementary Reversible Reactions

For a homogeneous stoichiometric reversible reaction proceeding in a closed isothermal system of fixed volume, a heuristic equation are established by Garfinkle. The present paper demonstrats: For a type of elementary reversible reactions, affinity decay equations vs. 1/t have asymptotes with unique slope, despite initial concentrations of reactants and rate constants.