| Sm—PMBP配合物红外和拉曼光谱的研究及其螯合环结构的计算 |
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| 引用本文： | 刘清亮,李辉.Sm—PMBP配合物红外和拉曼光谱的研究及其螯合环结构的计算[J].中国科学技术大学学报,1993,23(4):489-492. |
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| 作者姓名： | 刘清亮 李辉 |
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| 作者单位： | 中国科学技术大学应用化学系
(刘清亮)，中国科学技术大学应用化学系(李辉) |
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| 摘 要： | 测定了配位体PMBP(1-苯基-3-甲基-4-苯基酰基吡唑酮-5)及它与Sm形成的配合物的红外和Raman光谱。对低波数的谱峰进行了比较合理的指认,同时利用简正频率的公式计算了配合物内螯合环的结构参数(键长和键角)。
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| 关 键 词： | 钐 红外光谱 拉曼光谱 配合物 结构计算 |
IR and Raman Spectra of Sm Complex, With PMBP and Structural Calculation of Its Chelate Ring |
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| Liu Qingliang Li Hui.IR and Raman Spectra of Sm Complex, With PMBP and Structural Calculation of Its Chelate Ring[J].Journal of University of Science and Technology of China,1993,23(4):489-492. |
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| Authors: | Liu Qingliang Li Hui |
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| Institution: | Department of Applied Chemistry |
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| Abstract: | IR and Raman Spectra of HPMBP and their complexs with Sm are determined respectively. The peaks in low wave number region are assigned, based on the observation of IR and Raman spectra of HPMBP, Sm-PMBP complex and Sm_2O_2. Some parameters related to the structure of the chelate ring, i. e. , the bond lengths and the bond angles are also calculated. |
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| Keywords: | IR spectrum Raman spectrum Sm structural calculation |
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