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Co/TiO2粒子的制备及其光催化降解罗丹明B的研究
引用本文:张锋,梁宇,刘国光,牛新书,姚琨.Co/TiO2粒子的制备及其光催化降解罗丹明B的研究[J].河南师范大学学报(自然科学版),2006,34(1):91-94,133.
作者姓名:张锋  梁宇  刘国光  牛新书  姚琨
作者单位:河南师范大学,化学与环境科学学院,河南省环境污染控制重点实验室,河南,新乡,453007;新乡师范高等专科学校,化学系,河南,新乡,453000
基金项目:河南省高校杰出科研创新人才工程项目
摘    要:通过溶胶—凝胶法制备掺杂Co2+的纳米TiO2,并用XRD和TEM进行了分析和表征.以汞灯为光源,通过对罗丹明B的降解反应,考察了Co2+/TiO2的光催化活性.结果表明,Co2+的掺杂减小了TiO2颗粒的粒径,提高了TiO2的光催化活性,Co2+惨杂量为1.0%时的光催化活性最高.另外,本文还研究了催化剂投加量对罗丹明B光催化降解效率的影响.

关 键 词:TiO2  Co  掺杂  光催化  罗丹明B
文章编号:1000-2367(2006)01-0091-04
收稿时间:2005-08-06
修稿时间:2005-08-06

Studies on Photocatalytic Degradation of Rhodamine B on Co/TiO2
ZHANG Feng,LIANG Yu,LIU Guo-guang,NIU Xin-shu,YAO Kun.Studies on Photocatalytic Degradation of Rhodamine B on Co/TiO2[J].Journal of Henan Normal University(Natural Science),2006,34(1):91-94,133.
Authors:ZHANG Feng  LIANG Yu  LIU Guo-guang  NIU Xin-shu  YAO Kun
Institution:1, College of Chemistry and Environmental Science, Henan Normal University;Henan Key Laboratory for Environmental Pollution Control,Xinxiang 453007 ,China ; 2, Department of Chemistry,Xinxiang Teachers College,Xinxiang 453000, China
Abstract:Co~(2 )-doped TiO_2 nanoparticles were prepared by sol-gel method and characterized by means of X-ray diffraction(XRD) and transmission electron microscopy(TEM).The activity of the prepared photocatalysts was investigated by degradation reaction of Rhodamine B radiated with mercury vapor lamp.Effects of amounts of TiO_2 and irradiation time on photocatalytic activity were also investigated.The results showed that the photocatalytic activity of Co~(2 )-doped TiO_2 was much higher than that of pure TiO_2 particles.The optimum value of the Co~(2 )/TiO_2 was 1.0% for the photocatalytic degradation of Rhodamine B.
Keywords:TiO2  Co  doping  photocatalysis  Rhodamine B
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