| 稀土配位聚合物的合成、结构和热分析性质(英文) |
| |
| 作者姓名： | ZHANG Xing-jing |
| |
| 作者单位： | 吉林师范大学化学学院 |
| |
| 基金项目： | National Natural Science Foundation(60978059);Natural Science Foundation of Jilin Province of China(20090527);Science and Technology Development Projects of Siping City(2010005) |
| |
| 摘 要： | 运用水热合成法合成一种稀土配位聚合物KDy(C4H4O4)0.5(C2O4)1.5(H2O)]H2O(1),该配合物属于正交晶系,Fddd空间群,晶胞参数a=8.8467(6),b=16.3167(11),c=7.2058(5),α=β=γ=90°,V=1040.15(12),Z=4,C5H6O10KDy,Mr=427.70,Dc=2.731g/cm3,μ=(MoKa)7.628mm-1,F(000)804,R1=0.0262和wR2=0.0697.并对该配合物的热重分析进行详细讨论.
|
| 关 键 词： | 镝(Ⅲ)配位聚合物 晶体结构 水热和成 热分析性质 |
A new lanthanide coordination polymers synthesis,structure and thermal property |
| |
| ZHANG Xing-jing.A new lanthanide coordination polymers synthesis,structure and thermal property[J].Journal of Science of Teachers＇College and University,2012(5):53-56. |
| |
| Authors: | ZHANG Xing-jing |
| |
| Institution: | School of Chemistry,Jilin Normal University,Siping 136000,China |
| |
| Abstract: | A new rare earth metal-organic frameworks,KDy(C4H4O4)0.5(C2O4)1.5(H2O)]H2O(1) have been synthesized under hydrothermal condition.The title complex crystallizes in Orthorhombic space group Fddd,with a=8.8467(6),b=16.3167(11),c=7.2058(5),α=β=γ=90°,V=1040.15(12),Z=4,C5H6O10KDy,Mr=427.70,Dc=2.731g/cm3,μ=(MoKa)7.628mm-1,F(000)804,R1=0.0262 and wR2=0.0697.The thermogravimetric analysis of 1 are discussed in detail. |
| |
| Keywords: | dysprosium(Ⅲ)coordination polymers crystal structure hydrothermal synthesis thermal properties |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
