| A novel heteroseneous reaction for generating gaseous nitrous acid |
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| 作者姓名： | WANG WeiGang GE MaoFa YAO Li ZENG XiaoQing WANG ZiFa |
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| 作者单位： | [1]Beijing National Laboratory for Molecular Sciences, and State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; [2]State Key laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chi- nese Academy of Sciences, Beijing 100029, China |
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| 基金项目： | Supported by the Knowledge Innovation Program of the Chinese Academy of Sciences （Grant No. KZCX2-YW-205） and Hundred Talents Fund, the 973 Program of Ministry of Science and Technology of China （Grant No. 2006CB403701）, the National Natural Science Foundation of China （Grant Nos. 20577052, 20673123, 20473094, and 20503035） |
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| 摘 要： | The short-lived reactive specimen nitrous acid HONO was generated in the gas phase by the heterogeneous reaction of gaseous HCl with AgNO2 which can generate higher concentration of HONO than other methods. We investigated the process from generation to dissociation in the gas phase under different controlled temperatures, and discussed the ionization and reaction on the solid surface by combination of the photoelectron spectroscopy and photoionization mass spectroscopy （PES-PIMS） and in situ diffuse reflectance infrared Fourier transform spectroscopy （DRIFTS）.
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| 关 键 词： | 亚硝酸 气体 网络技术异构性 化学结构 |
| 收稿时间： | 25 February 2007 |
| 修稿时间： | 2007-02-25 |
A novel heterogeneous reaction for generating gaseous nitrous acid |
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| WANG WeiGang GE MaoFa YAO Li ZENG XiaoQing WANG ZiFa.A novel heteroseneous reaction for generating gaseous nitrous acid[J].Chinese Science Bulletin,2007,52(22):3056-3060. |
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| Authors: | Wang WeiGang Ge MaoFa Yao Li Zeng XiaoQing Wang ZiFa |
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| Institution: | (1) Beijing National Laboratory for Molecular Sciences, and State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China;(2) State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China |
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| Abstract: | The short-lived reactive specimen nitrous acid HONO was generated in the gas phase by the heterogeneous reaction of gaseous
HCI with AgNO2 which can generate higher concentration of HONO than other methods. We investigated the process from generation to dissociation
in the gas phase under different controlled temperatures, and discussed the ionization and reaction on the solid surface by
combination of the photoelectron spectroscopy and photoionization mass spectroscopy (PES-PIMS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS).
Supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX2-YW-205) and Hundred Talents
Fund, the 973 Program of Ministry of Science and Technology of China (Grant No. 2006CB403701), the National Natural Science
Foundation of China (Grant Nos. 20577052, 20673123, 20473094, and 20503035) |
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| Keywords: | HONO PES-PIMS DRIFTS |
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