| 球形电极上阶梯扫描示差脉冲伏安法可逆波理论 |
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| 引用本文： | 于俊生 张祖训. 球形电极上阶梯扫描示差脉冲伏安法可逆波理论[J]. 南京大学学报(自然科学版), 1993, 29(4): 605-614 |
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| 作者姓名： | 于俊生 张祖训 |
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| 作者单位： | 南京大学化学系，南京大学化学系 |
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| 摘 要： | 本文推导了球形电极上阶梯扫描示差脉冲伏安法可逆波理论,利用悬汞电极和Cd(Ⅱ)-KCl体系及自制的微机多功能电分析仪进行实验验证,理论与实验结果十分符合。
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| 关 键 词： | 阶梯扫描示差脉冲伏安法 球形电极 可逆波理论 |
THE THEORY OF REVERSIBLE WAVE FOR STAIRCASE SWEEP DIFFERENTIAL PULSE VOLTAMMETRY AT SPHERICAL ELECTRODES |
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| Yu Junsheng Zhang Zuxun. THE THEORY OF REVERSIBLE WAVE FOR STAIRCASE SWEEP DIFFERENTIAL PULSE VOLTAMMETRY AT SPHERICAL ELECTRODES[J]. Journal of Nanjing University: Nat Sci Ed, 1993, 29(4): 605-614 |
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| Authors: | Yu Junsheng Zhang Zuxun |
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| Affiliation: | Department of Chemistry |
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| Abstract: | The equation of reversible wave for staircase sweep differential pulse voltammetry at spherical electrodes is derived. It is verified experimentally by electro-reduction of Cd(II) in the presence of KCl at a hanging mercury electrode. The instrument is a computerized multi-purpose voltammetric analyzer, and it was assembled in our laboratory by ourselves. The experimental results are in good agreement with the theoretical predictions. |
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| Keywords: | staircase sweep differential pulse voltammetry spherical electrode the theory of reversible wave |
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